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Equilibrium chemistry is concerned with systems in chemical equilibrium. The unifying principle is that the free energy of a system at equilibrium is the minimum possible, so that the slope of the free energy with respect to the reaction coordinate is zero. [1][2] This principle, applied to mixtures at equilibrium provides a definition of an ...
Chemical equilibrium. In a chemical reaction, chemical equilibrium is the state in which both the reactants and products are present in concentrations which have no further tendency to change with time, so that there is no observable change in the properties of the system. [1] This state results when the forward reaction proceeds at the same ...
In chemistry, Le Chatelier's principle (pronounced UK: / l ə ʃ æ ˈ t ɛ l j eɪ / or US: / ˈ ʃ ɑː t əl j eɪ /), also called Chatelier's principle, Braun–Le Chatelier principle, Le Chatelier–Braun principle or the equilibrium law, [1] is a principle used to predict the effect of a change in conditions on chemical equilibrium. [2]
Mechanical equilibrium. An object resting on a surface and the corresponding free body diagram showing the forces acting on the object. The normal force N is equal, opposite, and collinear to the gravitational force mg so the net force and moment is zero. Consequently, the object is in a state of static mechanical equilibrium.
Wulff construction. The Wulff construction is a method to determine the equilibrium shape of a droplet or crystal of fixed volume inside a separate phase (usually its saturated solution or vapor). Energy minimization arguments are used to show that certain crystal planes are preferred over others, giving the crystal its shape.
The Schlenk equilibrium, named after its discoverer Wilhelm Schlenk, is a chemical equilibrium taking place in solutions of Grignard reagents [1][2] and Hauser bases [3][4] 2 RMgX ⇌ MgX 2 + MgR 2. The process described is an equilibrium between two equivalents of an alkyl or aryl magnesium halide on the left of the equation and one equivalent ...
Lever rule. In chemistry, the lever rule is a formula used to determine the mole fraction (xi) or the mass fraction (wi) of each phase of a binary equilibrium phase diagram. It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line.
Maxwell construction. In thermodynamic equilibrium, a necessary condition for stability is that pressure, , does not increase with volume, or molar volume, ; this is expressed mathematically as , where is the temperature. [1] This basic stability requirement, and similar ones for other conjugate pairs of variables, is violated in analytic ...