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The electron is a charged particle with charge − e, where e is the unit of elementary charge. Its angular momentum comes from two types of rotation: spin and orbital motion. From classical electrodynamics, a rotating distribution of electric charge produces a magnetic dipole, so that it behaves like a tiny bar magnet.
The Weiss magneton was experimentally derived in 1911 as a unit of magnetic moment equal to 1.53 × 10 −24 joules per tesla, which is about 20% of the Bohr magneton. In the summer of 1913, the values for the natural units of atomic angular momentum and magnetic moment were obtained by the Danish physicist Niels Bohr as a consequence of his ...
The spin magnetic moment of the electron is =, where is the spin (or intrinsic angular-momentum) vector, is the Bohr magneton, and = is the electron-spin g-factor. Here μ {\displaystyle {\boldsymbol {\mu }}} is a negative constant multiplied by the spin , so the spin magnetic moment is antiparallel to the spin.
The magnetic moment of the electron is =, where μ B is the Bohr magneton, S is electron spin, and the g-factor g S is 2 according to Dirac's theory, but due to quantum electrodynamic effects it is slightly larger in reality: 2.002 319 304 36.
Crystal field diagram for octahedral low-spin d 5 Crystal field diagram for octahedral high-spin d 5. According to crystal field theory, the d orbitals of a transition metal ion in an octahedal complex are split into two groups in a crystal field. If the splitting is large enough to overcome the energy needed to place electrons in the same ...
For a magnetic crystal, it is tempting to try to define = where the limit is taken as the volume V of the system becomes large. However, because of the factor of r in the integrand, the integral has contributions from surface currents that cannot be neglected, and as a result the above equation does not lead to a bulk definition of orbital magnetization.
Free electrons possess electric charge and magnetic moment whose absolute value is about one Bohr magneton.. The standard electron spin resonance, also known as electron paramagnetic resonance (EPR), is due to the coupling of electron magnetic moment to the external magnetic field through the Hamiltonian = describing its Larmor precession.
where is the Bohr magneton, is the total electronic angular momentum, and is the Landé g-factor. A more accurate approach is to take into account that the operator of the magnetic moment of an electron is a sum of the contributions of the orbital angular momentum L → {\displaystyle {\vec {L}}} and the spin angular momentum S → ...