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[1] [2] [3] It is a measure of the average molecular weight (or chain length) of all the fatty acids present in the sample in form of triglycerides. The higher the saponification value, the lower the fatty acids average length, the lighter the mean molecular weight of triglycerides and vice versa.
Saponification is a process of cleaving esters into carboxylate salts and alcohols by the action of aqueous alkali. Typically aqueous sodium hydroxide solutions are used. [1] [2] It is an important type of alkaline hydrolysis. When the carboxylate is long chain, its salt is called a soap. The saponification of ethyl acetate gives sodium acetate ...
The value gives an approximation for the content of aromatic compounds in the oil, [2] since the miscibility of aniline, which is also an aromatic compound suggests the presence of similar (i.e. aromatic) compounds in the oil. The lower the aniline point, the greater is the content of aromatic compounds in the oil.
An example is the determination of free fatty acid content. Saponification value: the mass in milligrams of KOH required to saponify a fatty acid in one gram of sample. Saponification is used to determine average chain length of fatty acids in fat. Ester value (or ester index): a calculated index. Ester value = Saponification value – Acid value.
Where HV is the hydroxyl value; V B is the amount (ml) potassium hydroxide solution required for the titration of the blank; V acet is the amount (ml) of potassium hydroxide solution required for the titration of the acetylated sample; W acet is the weight of the sample (in grams) used for acetylation; N is the normality of the titrant; 56.1 is ...
The Reichert value is an indicator of how much volatile fatty acid can be extracted from a particular fat or oil through saponification. It is equal to the number of millilitres of 0.1 normal hydroxide solution necessary for the neutralization of the water-soluble volatile fatty acids distilled and filtered from 5 grams of a given saponified fat.
It is an indicator of how much volatile fatty acid can be extracted from fat through saponification. It is equal to the number of milliliters of 0.1 normal alkali solution necessary for the neutralization of the water-insoluble volatile fatty acids distilled and filtered from 5 grams of a given saponified fat.
Structural Formula Lipid Numbers Propionic acid: Propanoic acid CH 3 CH 2 COOH C3:0 Butyric acid: Butanoic acid CH 3 (CH 2) 2 COOH C4:0 Valeric acid: Pentanoic acid CH 3 (CH 2) 3 COOH C5:0 Caproic acid: Hexanoic acid CH 3 (CH 2) 4 COOH C6:0 Enanthic acid: Heptanoic acid CH 3 (CH 2) 5 COOH C7:0 Caprylic acid: Octanoic acid CH 3 (CH 2) 6 COOH C8 ...