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kT (also written as k B T) is the product of the Boltzmann constant, k (or k B), and the temperature, T.This product is used in physics as a scale factor for energy values in molecular-scale systems (sometimes it is used as a unit of energy), as the rates and frequencies of many processes and phenomena depend not on their energy alone, but on the ratio of that energy and kT, that is, on E ...
Given a thermodynamic system at an absolute temperature T, the average thermal energy carried by each microscopic degree of freedom in the system is 1 / 2 kT (i.e., about 2.07 × 10 −21 J, or 0.013 eV, at room temperature).
[2] [7] [8] The 2019 revision of the SI now defines the kelvin in terms of energy by setting the Boltzmann constant to exactly 1.380 649 × 10 −23 joules per kelvin; [2] every 1 K change of thermodynamic temperature corresponds to a thermal energy change of exactly 1.380 649 × 10 −23 J.
The term "thermal energy" is often used ambiguously in physics and engineering. [1] It can denote several different physical concepts, including: Internal energy : The energy contained within a body of matter or radiation, excluding the potential energy of the whole system, and excluding the kinetic energy of the system moving as a whole.
In non-thermal units, it can also be measured in byte per joule, or more conveniently, gigabyte per nanojoule; [3] 1 K −1 is equivalent to about 13,062 gigabytes per nanojoule; at room temperature: T = 300K, β ≈ 44 GB/nJ ≈ 39 eV −1 ≈ 2.4 × 10 20 J −1. The conversion factor is 1 GB/nJ = J −1.
The theoretical temperature is determined by extrapolating the ideal gas law; by international agreement, absolute zero is taken as 0 kelvin (International System of Units), which is −273.15 degrees on the Celsius scale, [1] [2] and equals −459.67 degrees on the Fahrenheit scale (United States customary units or imperial units). [3]
For gases, departure from 3 R per mole of atoms is generally due to two factors: (1) failure of the higher quantum-energy-spaced vibration modes in gas molecules to be excited at room temperature, and (2) loss of potential energy degree of freedom for small gas molecules, simply because most of their atoms are not bonded maximally in space to ...
Thermodynamic temperature is a quantity defined in thermodynamics as distinct from kinetic theory or statistical mechanics.. Historically, thermodynamic temperature was defined by Lord Kelvin in terms of a macroscopic relation between thermodynamic work and heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are ...