Search results
Results from the WOW.Com Content Network
The covalent radius of fluorine of about 71 picometers found in F 2 molecules is significantly larger than that in other compounds because of this weak bonding between the two fluorine atoms. [9] This is a result of the relatively large electron and internuclear repulsions, combined with a relatively small overlap of bonding orbitals arising ...
In inorganic chemistry, Fajans' rules, formulated by Kazimierz Fajans in 1923, [1] [2] [3] are used to predict whether a chemical bond will be covalent or ionic, and depend on the charge on the cation and the relative sizes of the cation and anion. They can be summarized in the following table:
Bonds to fluorine have considerable ionic character, a result of its small atomic radius and large electronegativity. Therefore, the bond length of F is influenced by its ionic radius, the size of ions in an ionic crystal, which is about 133 pm for fluoride ions. The ionic radius of fluoride is much larger than its covalent radius.
Solid HF consists of zig-zag chains of HF molecules. The HF molecules, with a short covalent H–F bond of 95 pm length, are linked to neighboring molecules by intermolecular H–F distances of 155 pm. [4] Liquid HF also consists of chains of HF molecules, but the chains are shorter, consisting on average of only five or six molecules. [5]
The carbon–fluorine bond is a polar covalent bond between carbon and fluorine that is a component of all organofluorine compounds. It is one of the strongest single bonds in chemistry (after the B–F single bond, Si–F single bond, and H–F single bond), and relatively short, due to its partial ionic character.
Alkali metals form ionic and highly soluble monofluorides; these have the cubic arrangement of sodium chloride and analogous chlorides. [ 102 ] [ 103 ] Alkaline earth difluorides possess strong ionic bonds but are insoluble in water, [ 86 ] with the exception of beryllium difluoride , which also exhibits some covalent character and has a quartz ...
Fluoride (/ ˈ f l ʊər aɪ d, ˈ f l ɔːr-/) [3] is an inorganic, monatomic anion of fluorine, with the chemical formula F − (also written [F] −), whose salts are typically white or colorless.
Lithium fluoride is an inorganic compound with the chemical formula LiF. It is a colorless solid that transitions to white with decreasing crystal size. Its structure is analogous to that of sodium chloride, but it is much less soluble in water.