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Each mole of CO 2 (44 g) reacts with one mole of calcium hydroxide (74 g) and produces one mole of water (18 g). The reaction can be considered as a strong-base-catalysed, water-facilitated reaction. [5] The reaction mechanism of carbon dioxide with soda lime can be decomposed in three elementary steps:
Carbonatation is a slow process that occurs in concrete where lime (CaO, or Ca(OH) 2 ) in the cement reacts with carbon dioxide (CO 2) from the air and forms calcium carbonate. The water in the pores of Portland cement concrete is normally alkaline with a pH in the range of 12.5 to 13.5.
Calcium hydroxide is moderately soluble in water, as seen for many dihydroxides. Its solubility increases from 0.66 g/L at 100 °C to 1.89 g/L at 0 °C. [8] Its solubility product K sp of 5.02 × 10 −6 at 25 °C, [1] its dissociation in water is large enough that its solutions are basic according to the following dissolution reaction:
This is accomplished by heating the material to above 825 °C (1,517 °F), [6] [7] a process called calcination or lime-burning, to liberate a molecule of carbon dioxide (CO 2), leaving quicklime behind. This is also one of the few chemical reactions known in prehistoric times. [8] CaCO 3 (s) → CaO(s) + CO 2 (g)
Pure lime is soluble in water containing carbonic acid, a natural, weak acid which is a solution of carbon dioxide in water and acid rain so it will slowly wash away, but this characteristic also produces autogenous or self-healing process where the dissolved lime can flow into cracks in the material and be redeposited, automatically repairing ...
Calcium carbonate reacts with water that is saturated with carbon dioxide to form the soluble calcium bicarbonate. CaCO 3 (s) + CO 2 (g) + H 2 O(l) → Ca(HCO 3 ) 2 (aq) This reaction is important in the erosion of carbonate rock , forming caverns , and leads to hard water in many regions.
This contrasts with calcium hydroxide, also called slaked lime or air lime that is used to make lime mortar, the other common type of lime mortar, which sets by carbonation (re-absorbing carbon dioxide (CO 2) from the air). Hydraulic lime provides a faster initial set and higher compressive strength than air lime, and hydraulic lime will set in ...
As lime in the form of limewater is added to raw water, the pH is raised and the equilibrium of carbonate species in the water is shifted. Dissolved carbon dioxide (CO 2) is changed into bicarbonate (HCO − 3) and then carbonate (CO 2-3). This action causes calcium carbonate to precipitate due to exceeding the solubility product.