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tert-Butyl peroxybenzoate (TBPB) an organic compound with the formula C 6 H 5 CO 3 CMe 3 (Me = CH 3). It is the most widely produced perester ; it is an ester of peroxybenzoic acid ( C 6 H 5 CO 3 H ).
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Peroxybenzoic acid is an organic compound with the formula C 6 H 5 CO 3 H. It is the simplest aryl peroxy acid.It may be synthesized from benzoic acid and hydrogen peroxide, [3] or by the treatment of benzoyl peroxide with sodium methoxide, followed by acidification.
tert-butyl hydroperoxide is potentially dangerous, but explosions are rare. [3]A solution of tert-butyl hydroperoxide and water with a concentration of greater than 90% is forbidden to be shipped according to US Department of Transportation Hazardous Materials Table 49 CFR 172.101.
The general structure of an organic peroxide. In organic chemistry, organic peroxides are organic compounds containing the peroxide functional group (R−O−O−R′).If the R′ is hydrogen, the compounds are called hydroperoxides, which are discussed in that article.
The Kharasch–Sosnovsky reaction is a method that involves using a copper or cobalt salt as a catalyst to oxidize olefins at the allylic position, subsequently condensing a peroxy ester (e.g. tert-Butyl peroxybenzoate) or a peroxide resulting in the formation of allylic benzoates or alcohols via radical oxidation. [1]
The benzoyl functional group.. In organic chemistry, benzoyl (/ ˈ b ɛ n z oʊ ɪ l /, BENZ-oh-il) [1] is the functional group with the formula −COC 6 H 5 and structure −C(=O)−C 6 H 5. [2] [3] It can be viewed as benzaldehyde missing one hydrogen.
In chemistry, radical initiators are substances that can produce radical species under mild conditions and promote radical reactions. [1] These substances generally possess weak bonds—bonds that have small bond dissociation energies.