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Nitric acid is an inorganic compound with the formula H N O 3. ... Upon reaction with nitric acid, most metals give the corresponding nitrates.
Mixture of nitric and acetic acids or nitric acid and acetic anhydride is commercially important in the production of RDX, as amines are destructed by sulfuric acid. Acetyl nitrate had also been used as a nitration agent. [14] [15] In the Wolffenstein–Böters reaction, benzene reacts with nitric acid and mercury(II) nitrate to give picric acid.
A number of side reactions compete with the formation of nitric oxide. Some reactions convert the ammonia to N 2, such as: 4NH 3 + 6NO → 5N 2 + 6H 2 O. This is a secondary reaction that is minimised by reducing the time the gas mixtures are in contact with the catalyst. [6] Another side reaction produces nitrous oxide:
Methyl nitrate can be produced on a laboratory or industrial scale either through the distillation of a mixture of methanol and nitric acid, or by the nitration of methanol by a mixture of sulfuric and nitric acids. The first procedure is not preferred due to the great explosion danger presented by the methyl nitrate vapour.
Urea nitrate is produced in one step by reaction of urea with nitric acid. This is an exothermic reaction, so steps must be taken to control the temperature. It was discovered in 1797 by William Cruickshank, [4] inventor of the Chloralkali process. Urea nitrate explosions may be initiated using a blasting cap. [3]
Nitrous acid is involved in the ozone budget of the lower atmosphere, the troposphere. The heterogeneous reaction of nitric oxide (NO) and water produces nitrous acid. When this reaction takes place on the surface of atmospheric aerosols, the product readily photolyses to hydroxyl radicals. [11] [12]
Most commonly, "mixed acid" (nitric and sulfuric acids) are used, but in the 1980s production of the nitrocellulose with magnesium nitrate as a dehydrating agent was started in the US. [4] In laboratory, phosphoric acid and phosphorus pentoxide or acetic acid and its anhydride may be used for the same purpose, or the nitroxylation can be ...
It hydrolyzes in moist air to acetic acid and nitric acid. Alternatively, nitric acid adds to ketene. [2] For aromatic nitrations, acetyl nitrate is generated in situ by mixing nitric acid with an excess of acetic anhydride in the presence of the aromatic substrate. [3] It acetylates amines, akin to the behavior of acetyl chloride: