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Boric acid is a weak acid, with pK a (the pH at which buffering is strongest because the free acid and borate ion are in equal concentrations) of 9.24 in pure water at 25 °C. But apparent p K a is substantially lower in swimming pool or ocean waters because of interactions with various other molecules in solution.
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Nitric acid, with a pK value of around −1.7, behaves as a strong acid in aqueous solutions with a pH greater than 1. [23] At lower pH values it behaves as a weak acid. pK a values for strong acids have been estimated by theoretical means. [24] For example, the pK a value of aqueous HCl has been estimated as −9.3.
Potassium fluoroborate is obtained by treating potassium carbonate with boric acid and hydrofluoric acid. B(OH) 3 + 4 HF → HBF 4 + 3 H 2 O 2 HBF 4 + K 2 CO 3 → 2 KBF 4 + H 2 CO 3. Fluoroborates of alkali metals and ammonium ions crystallize as water-soluble hydrates with the exception of potassium, rubidium, and cesium.
Borax "dihydrate" has the formula Na 2 B 4 O 7 ·2H 2 O, which is actually anhydrous, with the correct formula Na 2 B 4 O 5 (OH) 4. It can be obtained by heating the "decahydrate" or "pentahydrate" to above 116-120 °C. [20] Anhydrous borax is sodium tetraborate proper, with formula Na 2 B 4 O 7. It can be obtained by heating any hydrate to 300 ...
The term acidity function is also used for measurements made on basic systems, and the term basicity function is uncommon. Hammett-type acidity functions are defined in terms of a buffered medium containing a weak base B and its conjugate acid BH + :
The hydrated tetraborate anion occurs in the mineral borax (sodium tetraborate octahydrate) with the formula Na 2 [B 4 O 5 (OH) 4]·8H 2 O. The borax chemical formula is also commonly written in a more compact notation as Na 2 B 4 O 7 ·10H 2 O. Sodium borate can be obtained in high purity and so can be used to make a standard solution in ...
It consists of a mixture of 0.04 M boric acid, 0.04 M phosphoric acid and 0.04 M acetic acid that has been titrated to the desired pH with 0.2 M sodium hydroxide. Britton and Robinson also proposed a second formulation that gave an essentially linear pH response to added alkali from pH 2.5 to pH 9.2 (and buffers to pH 12).