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Toluene is also found in cigarette smoke and car exhaust. If not in contact with air, toluene can remain unchanged in soil or water for a long time. [39] Toluene is a common solvent, e.g. for paints, paint thinners, silicone sealants, [40] many chemical reactants, rubber, printing ink, adhesives (glues), lacquers, leather tanners, and ...
Physical and Chemical Properties of Toluene in chemeo.com This page was last edited on 12 April 2023, at 11:55 (UTC). Text is available under the Creative Commons ...
PubChem CID. 7463; RTECS number ... Chemical formula. C 10 H 14: Molar mass: ... Cymene is also produced by alkylation of toluene with propene. [4] Related compounds
Ethyltoluene is produced by ethylation of toluene: CH 3 C 6 H 5 + C 2 H 4 → CH 3 C 6 H 4 C 2 H 5. Over typical acid catalysts, this process gives a mixture of the 2-, 3-, and 4- isomers. Using a modified zeolite catalyst, the alkylation is shape-selective for the 4- isomer. [1] 4-Ethyltoluene is subjected dehydrogenation to give 4 ...
In organic synthesis, PPTS is used as a weakly acidic catalyst, providing an organic soluble source of pyridinium (C 5 H 5 NH +) ions.For example, PPTS is used to deprotect silyl ethers or tetrahydropyranyl ethers when a substrate is unstable to stronger acid catalysts.
Together with other isomers, 4-nitrotoluene is prepared by nitration of toluene, [4] commonly using titanium(IV) nitrate. [5] It undergoes the reactions typical for nitrobenzene derivatives, e.g. hydrogenation gives p-toluidine. Oxidation of the methyl substituent of 4-nitrotoluene has been extensively investigated.
According to Ogawa and Curran, trifluorotoluene is similar to dichloromethane in standard acylation, tosylation, and silylation reactions. [4] The dielectric constants for dichloromethane and trifluorotoluene are 9.04 and 9.18, respectively, indicating similar solvating properties.
Ethyltoluenes are prepared by alkylation of toluene with ethylene: CH 3 C 6 H 5 + CH 2 =CH 2 → CH 3 C 6 H 4 CH 2 CH 3. These alkylations are catalyzed by various Lewis acids, such as aluminium trichloride. 3- and 4-Ethyltoluenes are mainly of interest as precursors to methylstyrenes: CH 3 C 6 H 4 CH 2 CH 3 → CH 3 C 6 H 4 CH=CH 2 + H 2
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