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Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
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The pH range is commonly given as zero to 14, but a pH value can be less than 0 for very concentrated strong acids or greater than 14 for very concentrated strong bases. [ 2 ] The pH scale is traceable to a set of standard solutions whose pH is established by international agreement. [ 3 ]
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No description. Template parameters [Edit template data] This template prefers block formatting of parameters. Parameter Description Type Status indicator_name indicator_name no description Unknown optional low_pH low_pH no description Unknown optional high_pH high_pH no description Unknown optional low_pH_color low_pH_color no description Unknown optional low_pH_text low_pH_text no ...
Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
The standard hydrogen electrode (SHE), with [ H +] = 1 M works thus at a pH = 0. At pH = 7, when [ H +] = 10 −7 M, the reduction potential of H + differs from zero because it depends on pH. Solving the Nernst equation for the half-reaction of reduction of two protons into hydrogen gas gives: 2 H + + 2 e − ⇌ H 2