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SO 3 is the anhydride of H 2 SO 4. Thus, it is susceptible to hydration: SO 3 + H 2 O → H 2 SO 4 (Δ f H = −200 kJ/mol) [12] Gaseous sulfur trioxide fumes profusely even in a relatively dry atmosphere owing to formation of a sulfuric acid mist. SO 3 is aggressively hygroscopic. The heat of hydration is sufficient that mixtures of SO 3 and ...
[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
BF 3 + OMe 2 → BF 3 OMe 2. Both BF 4 − and BF 3 OMe 2 are Lewis base adducts of boron trifluoride. Many adducts violate the octet rule, such as the triiodide anion: I 2 + I − → I − 3. The variability of the colors of iodine solutions reflects the variable abilities of the solvent to form adducts with the Lewis acid I 2.
[2] Sulfamic acid (H 3 NSO 3) may be considered an intermediate compound between sulfuric acid (H 2 SO 4), and sulfamide (H 4 N 2 SO 2), effectively replacing a hydroxyl (–OH) group with an amine (–NH 2) group at each step. This pattern can extend no further in either direction without breaking down the sulfonyl (–SO 2 –) moiety.
As a salt of a strong acid (H 2 SO 4) and weak base (NH 3), its solution is acidic; the pH of 0.1 M solution is 5.5. In aqueous solution the reactions are those of NH + 4 and SO 2− 4 ions. For example, addition of barium chloride, precipitates out barium sulfate. The filtrate on evaporation yields ammonium chloride.
In chemistry, a superacid (according to the original definition) is an acid with an acidity greater than that of 100% pure sulfuric acid (H 2 SO 4), [1] which has a Hammett acidity function (H 0) of −12. According to the modern definition, a superacid is a medium in which the chemical potential of the proton is higher than in pure sulfuric ...
The structure of the tetrathionate anion. The tetrathionate anion, S 4 O 2− 6, is a sulfur oxyanion derived from the compound tetrathionic acid, H 2 S 4 O 6. Two of the sulfur atoms present in the ion are in oxidation state 0 and two are in oxidation state +5. Alternatively, the compound can be viewed as the adduct resulting from the binding ...
Fluorosulfuric acid (IUPAC name: sulfurofluoridic acid) is the inorganic compound with the chemical formula HSO 3 F.It is one of the strongest acids commercially available. It is a tetrahedral molecule and is closely related to sulfuric acid, H 2 SO 4, substituting a fluorine atom for one of the hydroxyl groups.