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Perchloric acid forms an azeotrope with water, consisting of about 72.5% perchloric acid. This form of the acid is stable indefinitely and is commercially available. Such solutions are hygroscopic. Thus, if left open to the air, concentrated perchloric acid dilutes itself by absorbing water from the air.
Sodium perchlorate is an inorganic compound with the chemical formula Na Cl O 4.It consists of sodium cations Na + and perchlorate anions ClO − 4.It is a white crystalline, hygroscopic solid that is highly soluble in water and ethanol.
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As perchloric acid is one of the strongest mineral acids, perchlorate is a weak base in the sense of Brønsted–Lowry acid–base theory. As it is also generally a weakly coordinating anion , perchlorate is commonly used as a background , or supporting, electrolyte .
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The compound is prepared by treating hydrated rhodium(III) chloride and perchloric acid at elevated temperatures: [1] [Rh(H 2 O) 6]Cl 3 + 3 HClO 4 → [Rh(H 2 O) 6](ClO 4) 3 + 3 HCl. The reaction of rhodium(III) hydroxide with concentrated perchloric acid also produce rhodium(III) perchlorate. [2] Rh(OH) 3 + 3 HClO 4 → Rh(ClO 4) 3 + 3 H 2 O
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Potassium perchlorate in crystal form. Potassium perchlorate is prepared industrially by treating an aqueous solution of sodium perchlorate with potassium chloride.This single precipitation reaction exploits the low solubility of KClO 4, which is about 1/100 as much as the solubility of NaClO 4 (209.6 g/100 mL at 25 °C).
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