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In aqueous solutions, redox potential is a measure of the tendency of the solution to either gain or lose electrons in a reaction. A solution with a higher (more positive) reduction potential than some other molecule will have a tendency to gain electrons from this molecule (i.e. to be reduced by oxidizing this other molecule) and a solution with a lower (more negative) reduction potential ...
Definition Named after Field of application Activity coefficient = chemistry (Proportion of "active" molecules or atoms) Arrhenius number = Svante Arrhenius: chemistry (ratio of activation energy to thermal energy) [1]
The Planck relation [1] [2] [3] (referred to as Planck's energy–frequency relation, [4] the Planck–Einstein relation, [5] Planck equation, [6] and Planck formula, [7] though the latter might also refer to Planck's law [8] [9]) is a fundamental equation in quantum mechanics which states that the energy E of a photon, known as photon energy, is proportional to its frequency ν: =.
A pendulum with a period of 2.8 s and a frequency of 0.36 Hz. For cyclical phenomena such as oscillations, waves, or for examples of simple harmonic motion, the term frequency is defined as the number of cycles or repetitions per unit of time.
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the Van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
Calculable is the ratio of the populations of the two states at room temperature (T ≈ 300 K) for an energy difference ΔE that corresponds to light of a frequency corresponding to visible light (ν ≈ 5 × 10 14 Hz). In this case ΔE = E 2 − E 1 ≈ 2.07 eV, and kT ≈ 0.026 eV.
In continuum mechanics, the Péclet number (Pe, after Jean Claude Eugène Péclet) is a class of dimensionless numbers relevant in the study of transport phenomena in a continuum. It is defined to be the ratio of the rate of advection of a physical quantity by the flow to the rate of diffusion of the same quantity driven by an appropriate ...
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...