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First is the carbothermic reaction whereby the coal, a source of carbon, reduces the sulfate to sulfide: Na 2 SO 4 + 2 C → Na 2 S + 2 CO 2. In the second stage, is the reaction to produce sodium carbonate and calcium sulfide. This mixture is called black ash. [citation needed] Na 2 S + CaCO 3 → Na 2 CO 3 + CaS. The soda ash is extracted ...
Ammonium chloride precipitates and is removed by filtration, and the solution is recycled to produce more sodium carbonate. Hou's process eliminates the production of calcium chloride. The byproduct ammonium chloride can be refined, used as a fertilizer and may have greater commercial value than CaCl 2, thus reducing the extent of waste beds.
In 1792, the French chemist Nicolas Leblanc patented a process for producing sodium carbonate from salt, sulfuric acid, limestone, and coal. In the first step, sodium chloride is treated with sulfuric acid in the Mannheim process. This reaction produces sodium sulfate (salt cake) and hydrogen chloride:
Salt/common salt – a mineral, sodium chloride, NaCl, formed by evaporating seawater (impure form). Salt of tartar – potassium carbonate; also called potash. Salt of hartshorn/sal volatile – ammonium carbonate formed by distilling bones and horns. Tin salt – hydrated stannous chloride; see also spiritus fumans, another chloride of tin.
In the Gutzeit test, AsH 3 is generated by reduction of aqueous arsenic compounds, typically arsenites, with Zn in the presence of H 2 SO 4. The evolved gaseous AsH 3 is then exposed to AgNO 3 either as powder or as a solution. With solid AgNO 3, AsH 3 reacts to produce yellow Ag 4 AsNO 3, whereas AsH 3 reacts with a solution of AgNO 3 to give ...
It can also be prepared by chlorination of arsenic at 80–85 °C, but this method requires elemental arsenic. [4] 2 As + 3 Cl 2 → 2 AsCl 3. Arsenic trichloride can be prepared by the reaction of arsenic oxide and sulfur monochloride. This method requires simple apparatus and proceeds efficiently: [8] 2 As 2 O 3 + 6 S 2 Cl 2 → 4 AsCl 3 + 3 ...
Photomicrograph made with a scanning electron microscope and back-scatter detector: cross section of fly ash particles. Fly ash, flue ash, coal ash, or pulverised fuel ash (in the UK)—plurale tantum: coal combustion residuals (CCRs)—is a coal combustion product that is composed of the particulates that are driven out of coal-fired boilers together with the flue gases.
Molten salts (fluoride, chloride, and nitrate) can be used as heat transfer fluids as well as for thermal storage. This thermal storage is used in concentrated solar power plants. [8] [9] Molten-salt reactors are a type of nuclear reactor that uses molten salt(s) as a coolant or as a solvent in which the fissile material is dissolved ...