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In the Gutzeit test, AsH 3 is generated by reduction of aqueous arsenic compounds, typically arsenites, with Zn in the presence of H 2 SO 4. The evolved gaseous AsH 3 is then exposed to AgNO 3 either as powder or as a solution. With solid AgNO 3, AsH 3 reacts to produce yellow Ag 4 AsNO 3, whereas AsH 3 reacts with a solution of AgNO 3 to give ...
The ingredients for this are readily available and inexpensive: salt brine (from inland sources or from the sea) and limestone (from quarries). The worldwide production of soda ash in 2005 was estimated at 42 million tonnes, [2] which is more than six kilograms (13 lb) per year for each person on Earth. Solvay-based chemical plants now produce ...
The hydrogen atoms in the arsinide anion may be substituted by organic or other groups which can then also produce ions, for example by methyl −CH 3, like in potassium methyl arsinide (K + CH 3 AsH −), [12] or by trimethylsilyl −Si(CH 3) 3. [1] The doubly bonded ligand =AsH (or AsH 2−) is called arsinidene. [11]
First is the carbothermic reaction whereby the coal, a source of carbon, reduces the sulfate to sulfide: Na 2 SO 4 + 2 C → Na 2 S + 2 CO 2. In the second stage, is the reaction to produce sodium carbonate and calcium sulfide. This mixture is called black ash. [citation needed] Na 2 S + CaCO 3 → Na 2 CO 3 + CaS. The soda ash is extracted ...
One of the simplest arsenic compounds is the trihydride, the highly toxic, flammable, pyrophoric arsine (AsH 3). This compound is generally regarded as stable, since at room temperature it decomposes only slowly. At temperatures of 250–300 °C decomposition to arsenic and hydrogen is rapid. [34]
The most reactive metals, such as sodium, will react with cold water to produce hydrogen and the metal hydroxide: 2 Na (s) + 2 H 2 O (l) →2 NaOH (aq) + H 2 (g) Metals in the middle of the reactivity series, such as iron , will react with acids such as sulfuric acid (but not water at normal temperatures) to give hydrogen and a metal salt ...
A typical hydrogen demand is ~80 kg [citation needed] hydrogen per ton of dry, ash-free coal. Generally, this process is similar to hydrogenation. The output is at three levels: heavy oil, middle oil, gasoline. The middle oil is hydrogenated in order to get more gasoline and the heavy oil is mixed with the coal again and the process restarts.
Coal liquefaction is a process of converting coal into liquid hydrocarbons: liquid fuels and petrochemicals. This process is often known as "coal to X" or "carbon to X", where X can be many different hydrocarbon-based products. However, the most common process chain is "coal to liquid fuels" (CTL). [1]