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AFm form inter alia when tricalcium aluminate 3CaO·Al 2 O 3, or C 3 A in CCN, reacts with dissolved calcium sulfate (CaSO 4), or calcium carbonate (CaCO 3). As the sulfate form is the dominant one in AFm phases in the hardened cement paste (HCP) in concrete, AFm is often simply referred to as Aluminate Ferrite monosulfate or calcium aluminate ...
The attack arises from soils containing SO2−. 4 ions, such as MgSO 4 or Na 2 SO 4 soluble and hygroscopic salts. The tricalcium aluminate (C 3 A) hydrates first interact with sulfate ions to form ettringite (AFt). Ettringite crystallizes into small acicular needles slowly growing in the concrete pores. Once the pores are completely filled ...
Calcium aluminates can form complex salts in combination with different types of anions.Two series of calcium aluminates are known in cement chemistry: AFm and AFt phases, being respectively mono- or tri-substituted with a given divalent anion X (e.g. SO 2− 4, CO 2− 3, or hosting a divalent impurity such as SeO 2− 4 [3]...), or with two units of a monovalent anion, e.g. OH −, Cl − ...
3S) (blue) and belite (C. 2S) (orange) crystals. These are false (interference) colors. Calcium aluminoferrite (Ca. 2(Al,Fe) 2O. 5) is a dark brown crystalline phase commonly found in cements. In the cement industry it is termed tetra-calcium aluminoferrite or ferrite. In cement chemist notation (CCN), it is abbreviated as C.
Friedel's salt could be first tentatively represented as an AFm phase in which two chloride ions would have simply replaced one sulfate ion. This conceptual representation based on the intuition of a simple stoichiometric exchange is very convenient to remind but such a simple mechanism likely does not directly occur and must be considered with caution:
Atomic force microscopy [ 1 ] (AFM) is a type of SPM, with demonstrated resolution on the order of fractions of a nanometer, more than 1000 times better than the optical diffraction limit. The information is gathered by "feeling" or "touching" the surface with a mechanical probe.
Topographic (left) and current (right) maps collected with CAFM on a polycrystalline HfO 2 stack. The images show very good spatial correlation. In microscopy, conductive atomic force microscopy (C-AFM) or current sensing atomic force microscopy (CS-AFM) is a mode in atomic force microscopy (AFM) that simultaneously measures the topography of a material and the electric current flow at the ...
Concrete fracture analysis is part of fracture mechanics that studies crack propagation and related failure modes in concrete. [17] As it is widely used in construction, fracture analysis and modes of reinforcement are an important part of the study of concrete, and different concretes are characterized in part by their fracture properties. [ 18 ]
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