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Number of isomers [3] [4] Number of isomers including stereoisomers [3] [5] Molecular Formula Name of straight chain Synonyms 1 1 1 CH 4: methane: methyl hydride; natural gas 2 1 1 C 2 H 6: ethane: dimethyl; ethyl hydride; methyl methane 3 1 1 C 3 H 8: propane: dimethyl methane; propyl hydride 4 2 2 C 4 H 10: n-butane: butyl hydride ...
The number of possible isomers increases rapidly with the number of carbon atoms. For example, for acyclic alkanes: [3] C 1: methane only; C 2: ethane only; C 3: propane only; C 4: 2 isomers: butane and isobutane; C 5: 3 isomers: pentane, isopentane, and neopentane; C 6: 5 isomers: hexane, 2-methylpentane, 3-methylpentane, 2,2-dimethylbutane ...
One study found a mean of 4.5 ppm in the exhaled breath of test subjects. [19] The mean endogenous methanol in humans of 0.45 g/d may be metabolized from pectin found in fruit; one kilogram of apple produces up to 1.4 g of pectin (0.6 g of methanol.) [20] Methanol is produced by anaerobic bacteria and phytoplankton. [21] [22]
The enzyme methane monooxygenase produces methanol from methane, but cannot be used for industrial-scale reactions. [19] Some homogeneously catalyzed systems and heterogeneous systems have been developed, but all have significant drawbacks. These generally operate by generating protected products which are shielded from overoxidation.
Functional isomers are structural isomers which have different functional groups, resulting in significantly different chemical and physical properties. [ 11 ] An example is the pair propanal H 3 C–CH 2 –C(=O)-H and acetone H 3 C–C(=O)–CH 3 : the first has a –C(=O)H functional group, which makes it an aldehyde , whereas the second has ...
The homologous series of straight-chained alkanes begins methane (CH 4), ethane (C 2 H 6), propane (C 3 H 8), butane (C 4 H 10), and pentane (C 5 H 12). In that series, successive members differ in mass by an extra methylene bridge (-CH 2 - unit) inserted in the chain. Thus the molecular mass of each member differs by 14 atomic mass units ...
The required methanol is obtained from synthesis gas . [7] Other possible improvements call for a dual catalyst system that permits both methanol synthesis and dehydration in the same process unit, with no methanol isolation and purification. [7] [8] Both the one-step and two-step processes above are commercially available. The two-step process ...
Alcohols have a long history of myriad uses. For simple mono-alcohols, which is the focus on this article, the following are most important industrial alcohols: [25] methanol, mainly for the production of formaldehyde and as a fuel additive; ethanol, mainly for alcoholic beverages, fuel additive, solvent, and to sterilize hospital instruments. [26]