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Volumes of balls in dimensions 0 through 25; unit ball in red. In geometry, a ball is a region in a space comprising all points within a fixed distance, called the radius, from a given point; that is, it is the region enclosed by a sphere or hypersphere. An n-ball is a ball in an n-dimensional Euclidean space.
More generally, the unit -sphere is an -sphere of unit radius in (+)-dimensional Euclidean space; the unit circle is a special case, the unit -sphere in the plane. An ( open ) unit ball is the region inside of a unit sphere, the set of points of distance less than 1 from the center.
In chemistry, a formula unit is the smallest unit of a non-molecular substance, such as an ionic compound, covalent network solid, or metal. [1] [2] It can also refer to the chemical formula for that unit. Those structures do not consist of discrete molecules, and so for them, the term formula unit is used.
A ball in n dimensions is called a hyperball or n-ball and is bounded by a hypersphere or (n−1)-sphere. Thus, for example, a ball in the Euclidean plane is the same thing as a disk, the area bounded by a circle. In Euclidean 3-space, a ball is taken to be the volume bounded by a 2-dimensional sphere. In a one-dimensional space, a ball is a ...
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
The maximum work is thus regarded as the diminution of the free, or available, energy of the system (Gibbs free energy G at T = constant, P = constant or Helmholtz free energy F at T = constant, V = constant), whilst the heat given out is usually a measure of the diminution of the total energy of the system (internal energy).
For hydrocarbons, the DBE (or IHD) tells us the number of rings and/or extra bonds in a non-saturated structure, which equals the number of hydrogen pairs that are required to make the structure saturated, simply because joining two elements to form a ring or adding one extra bond (e.g., a single bond changed to a double bond) in a structure reduces the need for two H's.
Section 3.8 introduces atomic units and gives a table of atomic units of various physical quantities and the conversion factor to the SI units. Section 7.3(v) gives a concise but clear tutorial on practical use of atomic units, in particular how to understand equations "written in atomic units".