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To attempt to simplify and to stylize a very complex set of various reactions, the whole ASR reaction, after its complete evolution (ageing process) in the presence of sufficient Ca 2+ cations available in solution, could be compared to the pozzolanic reaction which would be catalysed by the undesirable presence of excessive concentrations of alkali hydroxides (NaOH and KOH) in the concrete.
For tanks with a concrete ringwall, a sand bed and a liner, the VCI is typically installed as an aqueous solution. The solution is either injected at minimal pressure through the leak detection ports, (distribution of the solution through the sand is primarily via capillary action) or through a preinstalled distribution system of perforated ...
A metal ion in aqueous solution or aqua ion is a cation, dissolved in water, of chemical formula [M(H 2 O) n] z+. The solvation number , n , determined by a variety of experimental methods is 4 for Li + and Be 2+ and 6 for most elements in periods 3 and 4 of the periodic table .
An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula . For example, a solution of table salt , also known as sodium chloride (NaCl), in water would be represented as Na + (aq) + Cl − (aq) .
[10]: 90–1 In aqueous solution, the alkali metal ions exist as octahedral hexahydrate complexes [M(H 2 O) 6] +, with the exception of the lithium ion, which due to its small size forms tetrahedral tetrahydrate complexes [Li(H 2 O) 4] +; the alkali metals form these complexes because their ions are attracted by electrostatic forces of ...
If gypsum is present in excess in concrete, it reacts with the monosulfate aluminates to form ettringite: C 3 A·3CŜ·H 12 + 2 CSH 2 + 16 H → C 3 A·3CŜ·H 32 A fairly well-defined reaction front can often be observed in thin sections ; ahead of the front the concrete is normal, or near normal.
Solutions of metal aquo complexes are acidic owing to the ionization of protons from the water ligands. In dilute solution chromium(III) aquo complex has a pK a of about 4.3, affording a metal hydroxo complex: [Cr(H 2 O) 6] 3+ ⇌ [Cr(H 2 O) 5 (OH)] 2+ + H + Thus, the aquo ion is a weak acid, of comparable strength to acetic acid (pK a of about ...
Metallic ions in aqueous solution display many colours: • the red cobalt cation Co 2+ from Co(NO 3) 2 (see § Co) • the orange chromium oxyanion Cr 2 O 2− 7 from K 2 Cr 2 O 7 • the yellow chromium oxyanion CrO 2− 4 from K 2 CrO 4 • the turquoise nickel cation Ni 2+ from NiCl 2
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