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In the International System of Units (SI), the coherent unit for molar concentration is mol/m 3. However, most chemical literature traditionally uses mol/dm 3, which is the same as mol/L. This traditional unit is often called a molar and denoted by the letter M, for example: 1 mol/m 3 = 10 −3 mol/dm 3 = 10 −3 mol/L = 10 −3 M = 1 mM = 1 ...
In chemistry, the molar mass (M) (sometimes called molecular weight or formula weight, but see related quantities for usage) of a chemical compound is defined as the ratio between the mass and the amount of substance (measured in moles) of any sample of the compound. [1] The molar mass is a bulk, not molecular, property of a substance.
For example, water has a molar mass of 18.0153(3) g/mol, but individual water molecules have molecular masses which range between 18.010 564 6863(15) Da (1 H 2 16 O) and 22.027 7364(9) Da (2 H 2 18 O). Atomic and molecular masses are usually reported in daltons, which is defined in terms of the mass of the isotope 12 C (carbon-12).
The molar mass of a substance depends not only on its molecular formula, but also on the distribution of isotopes of each chemical element present in it. For example, the molar mass of calcium-40 is 39.962 590 98 (22) g/mol, whereas the molar mass of calcium-42 is 41.958 618 01 (27) g/mol, and of calcium with the normal isotopic mix is 40.078(4 ...
For convenience in avoiding conversions in the imperial (or US customary units), some engineers adopted the pound-mole (notation lb-mol or lbmol), which is defined as the number of entities in 12 lb of 12 C. One lb-mol is equal to 453.592 37 g‑mol, [6] which is the same numerical value as the number of grams in an international avoirdupois pound.
M denotes the non-SI unit molar: 1 M = 1 mol/L = 10 −3 mol/m 3. All orders. List of orders of magnitude for molar concentration; Factor (Molarity) SI prefix Value
Thus, molecular mass and molar mass differ slightly in numerical value and represent different concepts. Molecular mass is the mass of a molecule, which is the sum of its constituent atomic masses. Molar mass is an average of the masses of the constituent molecules in a chemically pure but isotopically heterogeneous ensemble.
The mass-average molecular mass, M w, is also related to the fractional monomer conversion, p, in step-growth polymerization (for the simplest case of linear polymers formed from two monomers in equimolar quantities) as per Carothers' equation: ¯ = + ¯ = (+), where M o is the molecular mass of the repeating unit.