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The molar volume of a mixture can be found from the sum of the excess volumes of the components of a mixture: = (+ ¯). This formula holds because there is no change in volume upon mixing for an ideal mixture. The molar entropy, in contrast, is given by
The volume of such a mixture is slightly less than the sum of the volumes of the components. Thus, by the above definition, the term "40% alcohol by volume" refers to a mixture of 40 volume units of ethanol with enough water to make a final volume of 100 units, rather than a mixture of 40 units of ethanol with 60 units of water.
The following formulas can be used to calculate the volumes of solute (V solute) and solvent (V solvent) to be used: [1] = = where V total is the desired total volume, and F is the desired dilution factor number (the number in the position of F if expressed as "1/F dilution factor" or "xF dilution"). However, some solutions and mixtures take up ...
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...
When one mole of water is added to a large volume of water at 25 °C, the volume increases by 18 cm 3. The molar volume of pure water would thus be reported as 18 cm 3 mol −1. However, addition of one mole of water to a large volume of pure ethanol results in an increase in volume of only 14 cm 3. The reason that the increase is different is ...
A molecular formula enumerates the number of atoms to reflect those in the molecule, so that the molecular formula for glucose is C 6 H 12 O 6 rather than the glucose empirical formula, which is CH 2 O. Except for the very simple substances, molecular chemical formulas generally lack needed structural information, and might even be ambiguous in ...
The volume concentration (not to be confused with volume fraction [3]) is defined as the volume of a constituent divided by the volume of the mixture : =. Being dimensionless, it is expressed as a number, e.g., 0.18 or 18%.
where is the volume of the pure solvent before adding the solute and ~ its molar volume (at the same temperature and pressure as the solution), is the number of moles of solvent, ~ is the apparent molar volume of the solute, and is the number of moles of the solute in the solution. By dividing this ...