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Consequently, the object is in a state of static mechanical equilibrium. In classical mechanics, a particle is in mechanical equilibrium if the net force on that particle is zero. [1]: 39 By extension, a physical system made up of many parts is in mechanical equilibrium if the net force on each of its individual parts is zero. [1]: 45–46 [2]
For an object to be in static equilibrium, not only must the sum of the forces be zero, but also the sum of the torques (moments) about any point. For a two-dimensional situation with horizontal and vertical forces, the sum of the forces requirement is two equations: Σ H = 0 and Σ V = 0 , and the torque a third equation: Σ τ = 0 .
A state of mechanical equilibrium is stable if, when the position of the body is changed slightly, the body remains near that equilibrium. Otherwise, the equilibrium is unstable. A common visual representation of forces acting in concert is the free body diagram , which schematically portrays a body of interest and the forces applied to it by ...
In chemical kinetics, relaxation methods are used for the measurement of very fast reaction rates. A system initially at equilibrium is perturbed by a rapid change in a parameter such as the temperature (most commonly), the pressure, the electric field or the pH of the solvent. The return to equilibrium is then observed, usually by ...
Assuming that only mechanical work is done, this simplifies to This means that for such a system when not in equilibrium, the Gibbs energy will always be decreasing, and in equilibrium, the infinitesimal change dG will be zero. In particular, this will be true if the system is experiencing any number of internal chemical reactions on its path ...
Equilibrant force. In mechanics, an equilibrant force is a force which brings a body into mechanical equilibrium. [1] According to Newton's second law, a body has zero acceleration when the vector sum of all the forces acting upon it is zero:
An adiabatic wall between the two systems is 'permeable' only to energy transferred as work; at mechanical equilibrium the rates of transfer of energy as work between them are equal and opposite. If the wall is a simple wall, then the rates of transfer of volume across it are also equal and opposite; and the pressures on either side of it are ...
The equilibrium state of a thermodynamic system is described by specifying its "state". The state of a thermodynamic system is specified by a number of extensive quantities , the most familiar of which are volume , internal energy , and the amount of each constituent particle ( particle numbers ).