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Fine ZnS powder is an efficient photocatalyst, which produces hydrogen gas from water upon illumination. Sulfur vacancies can be introduced in ZnS during its synthesis; this gradually turns the white-yellowish ZnS into a brown powder, and boosts the photocatalytic activity through enhanced light absorption.
Common phases include ZnS, SnS, CuS, and Cu 2 SnS 3. Identification of these phases is challenging by traditional methods like X-ray diffraction (XRD) due to the peak overlap of ZnS and Cu 2 SnS 3 with CZTS. Some impurities such as ZnS and Cu 8 GeS 6 can be selectively removed from the CZTS or CZGS by treatment with hot diluted HCl. [9]
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Zinc selenide is the inorganic compound with the formula ZnSe. It is a lemon-yellow solid although most samples have a duller color due to the effects of oxidation. It is an intrinsic semiconductor with a band gap of about 2.70 eV at 25 °C (77 °F), equivalent to a wavelength of 459 nm.
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