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Fine ZnS powder is an efficient photocatalyst, which produces hydrogen gas from water upon illumination. Sulfur vacancies can be introduced in ZnS during its synthesis; this gradually turns the white-yellowish ZnS into a brown powder, and boosts the photocatalytic activity through enhanced light absorption.
Zinc sulfide, ZnS, crystallizes in two closely related structures, the zincblende crystal structure and the Wurtzite crystal structure, which are common structures of compounds with the formula MA. Both Zn and S are tetrahedrally coordinated by the other ion. A useful property of ZnS is its phosphorescence.
BaS + ZnSO 4 → ZnS · BaSO 4. This route affords a product that is 29.4 wt % ZnS and 70.6 wt % BaSO 4. Variations exist, for example, more ZnS-rich materials are produced when zinc chloride is added to the mixture of zinc sulfate and barium sulfide. [1] Barium sulfide is produced by carbothermic reduction of barium sulfate.
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Common phases include ZnS, SnS, CuS, and Cu 2 SnS 3. Identification of these phases is challenging by traditional methods like X-ray diffraction (XRD) due to the peak overlap of ZnS and Cu 2 SnS 3 with CZTS. Some impurities such as ZnS and Cu 8 GeS 6 can be selectively removed from the CZTS or CZGS by treatment with hot diluted HCl. [9]
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