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Nickel (II) nitrate is the inorganic compound Ni(NO 3) 2 or any hydrate thereof. In the hexahydrate, the nitrate anions are not bonded to nickel. Other hydrates have also been reported: Ni(NO 3) 2. 9H 2 O, Ni(NO 3) 2. 4H 2 O, and Ni(NO 3) 2. 2H 2 O. [3] It is prepared by the reaction of nickel oxide with nitric acid: NiO + 2 HNO 3 + 5 H 2 O → ...
In the NO − 3 anion, the oxidation state of the central nitrogen atom is V (+5). This corresponds to the highest possible oxidation number of nitrogen. Nitrate is a potentially powerful oxidizer as evidenced by its explosive behaviour at high temperature when it is detonated in ammonium nitrate (NH 4 NO 3), or black powder, ignited by the shock wave of a primary explosive.
Being the conjugate base of a strong acid (nitric acid, pK a = -1.4), nitrate has modest Lewis basicity.Two coordination modes are common: unidentate and bidentate.Often, bidentate nitrate, denoted κ 2-NO 3, is bound unsymmetrically in the sense that one M-O distance is clearly bonding and the other is more weakly interacting. [2]
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
The known salts include (NH 4) 2 Ni 2 (SO 4) 3, K 2 Ni 2 (SO 4) 3 and Rb 2 Ni 2 (SO 4) 3, and those of Tl and Cs are predicted to exist. Some minerals are double salts, for example Nickelzippeite Ni 2 (UO 2) 6 (SO 4) 3 (OH) 10 · 16H 2 O which is isomorphic to cobaltzippeite, magnesiozippeite and zinczippeite, part of the zippeite group. [43]
Nickel hydrazine nitrate (NHN), (chemical formula: [Ni(N 2 H 4) 3](NO 3) 2 is an energetic material having explosive properties in between that of primary explosive and a secondary explosive. [2] It is a salt of a coordination compound of nickel with a reaction equation of 3N 2 H 4 ·H 2 O + Ni(NO 3) 2 →〔Ni(N 2 H 4) 3 〕(NO 3) 2 ＋ 3H 2 O [3]
The PR64 specimen sold via Heritage Auctions in 2014 for nearly $3.3 million, while a PR63-graded example sold for almost $3.2 million in 2013 via the same auction house.
Zinc nitrate is an inorganic chemical compound with the formula Zn(NO 3) 2. This colorless, crystalline salt is highly deliquescent. It is typically encountered as a hexahydrate Zn(NO 3) 2 ·6H 2 O. It is soluble in both water and alcohol.