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Acid–base reactions typically occur faster than any other step which may determine the product of a reaction. The conjugate base is more electron-rich than the molecule which can alter the reactivity of the molecule. For example, deprotonation of an alcohol forms the negatively charged alkoxide, which is a much stronger nucleophile.
The following is a breakdown of the energetics of the photosynthesis process from Photosynthesis by Hall and Rao: [6]. Starting with the solar spectrum falling on a leaf, 47% lost due to photons outside the 400–700 nm active range (chlorophyll uses photons between 400 and 700 nm, extracting the energy of one 700 nm photon from each one)
The free energy created is then used, via a chain of nearby electron acceptors, for a transfer of hydrogen atoms (as protons and electrons) from H 2 O or hydrogen sulfide towards carbon dioxide, eventually producing glucose. These electron transfer steps ultimately result in the conversion of the energy of photons to chemical energy.
Photosynthesis (/ ˌ f oʊ t ə ˈ s ɪ n θ ə s ɪ s / FOH-tə-SINTH-ə-sis) [1] is a system of biological processes by which photosynthetic organisms, such as most plants, algae, and cyanobacteria, convert light energy, typically from sunlight, into the chemical energy necessary to fuel their metabolism.
The high-energy oxidized tyrosine gives off its energy and returns to the ground state by taking up a proton and removing an electron from the oxygen-evolving complex and ultimately from water. [4] Kok's S-state diagram shows the reactions of water splitting in the oxygen-evolving complex.
Calvin cycle step 1 (black circles represent carbon atoms) Calvin cycle steps 2 and 3 combined. The enzyme RuBisCO catalyses the carboxylation of ribulose-1,5-bisphosphate, RuBP, a 5-carbon compound, by carbon dioxide (a total of 6 carbons) in a two-step reaction. [6] The product of the first step is enediol-enzyme complex that can capture CO 2 ...
The complementary process, when a proton is removed from a Brønsted–Lowry acid, is deprotonation.) Some examples include The protonation of water by sulfuric acid: H 2 SO 4 + H 2 O ⇌ H 3 O + + HSO − 4; The protonation of isobutene in the formation of a carbocation: (CH 3) 2 C=CH 2 + HBF 4 ⇌ (CH 3) 3 C + + BF − 4
The underlying force driving these reactions is the Gibbs free energy of the reactants relative to the products. If donor and acceptor (the reactants) are of higher free energy than the reaction products, the electron transfer may occur spontaneously. The Gibbs free energy is the energy available ("free") to do work.