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3 in hydrochloric acid, is often used as a starting material for the synthesis of other Ir(III) compounds. [2] Another compound used as a starting material is ammonium hexachloroiridate(III), (NH 4) 3 IrCl 6. In the presence of air, iridium metal dissolves in molten alkali-metal cyanides to produce the Ir(CN) 3− 6 (hexacyanoiridate) ion.
Applications include their use as NMR "shift reagents" and as catalysts for organic synthesis, and precursors to industrial hydroformylation catalysts. C 5 H 7 O − 2 in some cases also binds to metals through the central carbon atom; this bonding mode is more common for the third-row transition metals such as platinum(II) and iridium(III).
Indium acetate is an acetate of indium, with the chemical formula In(CH 3 COO) 3. It is soluble in water, acetic acid and mineral acids. [ 1 ] It is the precursor of indium-containing compounds such as the solar cell materials CuInS 2 [ 2 ] and indium phosphide quantum dots .
Trimesityliridium is a pyramidal iridium(III) complex that crystallizes as a red-brown solid with the formula Ir(C 9 H 11) 3. [1] It is most often used as an oxygen atom transfer catalyst in concert with oxotrimesityliridium, the product it forms readily when exposed to O 2 .
Tris(acetylacetonato) iron(III), often abbreviated Fe(acac) 3, is a ferric coordination complex featuring acetylacetonate (acac) ligands, making it one of a family of metal acetylacetonates. It is a red air-stable solid that dissolves in nonpolar organic solvents.
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Iridium acetylacetonate is the iridium coordination complex with the formula Ir(O 2 C 5 H 7) 3, which is sometimes known as Ir(acac) 3. The molecule has D 3 -symmetry. [ 2 ] It is a yellow-orange solid that is soluble in organic solvents.
structure of the cation called basic iron acetate as determined from X-ray crystallography [4] Basic iron acetate forms on treating aqueous solutions of iron(III) sources with acetate salts. It is slowly soluble in water and poorly soluble in acetic acid. [5] A typical precursor is freshly precipitated iron oxide/hydroxide, which is halide-free ...