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It enabled the recovery and reuse of the inorganic pulping chemicals such that a kraft mill is a nearly closed-cycle process with respect to inorganic chemicals, apart from those used in the bleaching process. For this reason, in the 1940s, the kraft process superseded the sulfite process as the dominant method for producing wood pulp. [6]
The sulfite process is acidic and one of the drawbacks is that the acidic conditions hydrolyze some of the cellulose, which means that sulfite pulp fibers are not as strong as kraft pulp fibers. The yield of pulp (based on wood used) is higher than for kraft pulping and sulfite pulp is easier to bleach .
The kraft process does less damage to the cellulose fibers than the sulfite process, thereby producing stronger fibers, but the sulfite process makes pulp that is easier to bleach. The chemical pulping processes use a combination of high temperature and alkaline (kraft) or acidic (sulfite) chemicals to break the chemical bonds of the lignin.
The use of kraft recovery boilers spread fast as functioning chemical recovery gave kraft pulping an economic edge over sulfite pulping. [5] The first recovery boilers had horizontal evaporator surfaces, followed by superheaters and more evaporation surfaces. These boilers resembled the state-of-the-art boilers of some 30 years earlier.
Dissolving pulp is mainly produced chemically from pulpwood in a process that has a low yield (30 - 35% of the wood). This makes up of about 85 - 88% of the production. [2] Dissolving pulp is made from the sulfite process or the kraft process with an acid prehydrolysis step to remove hemicelluloses. For the highest quality, it should be derived ...
Chemical pulping involves dissolving lignin in order to extract the cellulose from the wood fiber. The different processes of chemical pulping include the Kraft process, which uses caustic soda and sodium sulfide and is the most common; alternatively, the use of sulfurous acid is known as the sulfite process, the neutral sulfite semichemical is treated as a third process separate from sulfite ...
Chemical pulp is used for materials that need to be stronger or combined with mechanical pulps to give a product different characteristics. The kraft process is the dominant chemical pulping method, with the sulfite process second. Historically soda pulping was the first successful chemical pulping method.
Chemical pulps, such as those from the kraft process or sulfite pulping, contain much less lignin than mechanical pulps, (<5% compared to approximately 40%). The goal in bleaching chemical pulps is to remove essentially all of the residual lignin, hence the process is often referred to as delignification.