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Moreover, 239 Pu and 240 Pu cannot be chemically distinguished, so expensive and difficult isotope separation would be necessary to separate them. Weapons-grade plutonium is defined as containing no more than 7% 240 Pu; this is achieved by only exposing 238 U to neutron sources for short periods of time to minimize the 240 Pu produced.
In contrast, the generic civilian Pressurized water reactor, routinely does (typical for 2015 Generation II reactor) 45 GWd/tU of burnup, resulting in the purity of Pu-239 being 50.5%, alongside a Pu-240 content of 25.2%, [5] [6] The remaining portion includes much more of the heat generating Pu-238 and Pu-241 isotopes than are to be found in ...
239 Pu is virtually nonexistent in nature. It is made by bombarding uranium-238 with neutrons. Uranium-238 is present in quantity in most reactor fuel; hence 239 Pu is continuously made in these reactors. Since 239 Pu can itself be split by neutrons to release energy, 239 Pu provides a portion of the energy generation in a nuclear reactor.
Pu-239 is produced artificially in nuclear reactors when a neutron is absorbed by U-238, forming U-239, which then decays in a rapid two-step process into Pu-239. [22] It can then be separated from the uranium in a nuclear reprocessing plant. [23] Weapons-grade plutonium is defined as being predominantly Pu-239, typically about 93% Pu-239. [24]
Neutrons from the fission of uranium-235 are captured by uranium-238 nuclei to form uranium-239; a beta decay converts a neutron into a proton to form neptunium-239 (half-life 2.36 days) and another beta decay forms plutonium-239. [28] Egon Bretscher working on the British Tube Alloys project predicted this reaction theoretically in 1940. [29]
Neptunium-239 has 146 neutrons and a half-life of 2.356 days. It is produced via β − decay of the short-lived uranium-239 , and undergoes another β − decay to plutonium-239 . This is the primary route for making plutonium, as 239 U can be made by neutron capture in uranium-238 .
Red: uranium-238, light green: plutonium-239, black: fission products. Intensity of blue color between the tiles indicates neutron density A traveling-wave reactor ( TWR ) is a proposed type of nuclear fission reactor that can convert fertile material into usable fuel through nuclear transmutation , in tandem with the burnup of fissile material.
Pu, and eventually fissile 239 Pu and heavier isotopes of plutonium. The 237 Np can be removed and stored as waste or retained and transmuted to plutonium, where more of it fissions, while the remainder becomes 242 Pu, then americium and curium, which in turn can be removed as waste or returned to reactors for further transmutation and fission.
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