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Acetone (2-propanone or dimethyl ketone) is an organic compound with the formula (CH 3) 2 CO. [22] It is the simplest and smallest ketone (>C=O).It is a colorless, highly volatile, and flammable liquid with a characteristic pungent odour, very reminiscent of the smell of pear drops.
Hydrogen-bonding-in-water. A hydrogen bond (H-bond), is a specific type of interaction that involves dipole–dipole attraction between a partially positive hydrogen atom and a highly electronegative, partially negative oxygen, nitrogen, sulfur, or fluorine atom (not covalently bound to said hydrogen atom).
The polarity is due to the electronegativity of the atom of oxygen: oxygen is more electronegative than the atoms of hydrogen, so the electrons they share through the covalent bonds are more often close to oxygen rather than hydrogen. These are called polar covalent bonds, covalent bonds between atoms that thus become oppositely charged. [1]
The carbonyl group is polar because the electronegativity of the oxygen is greater than that for carbon. Thus, ketones are nucleophilic at oxygen and electrophilic at carbon. Because the carbonyl group interacts with water by hydrogen bonding, ketones are typically more soluble in water than the related methylene compounds. Ketones are hydrogen ...
Not all atoms attract electrons with the same force. The amount of "pull" an atom exerts on its electrons is called its electronegativity.Atoms with high electronegativities – such as fluorine, oxygen, and nitrogen – exert a greater pull on electrons than atoms with lower electronegativities such as alkali metals and alkaline earth metals.
The bond between a water molecule and the metal ion is a dative covalent bond, with the oxygen atom donating both electrons to the bond. Each coordinated water molecule may be attached by hydrogen bonds to other water molecules. The latter are said to reside in the second coordination sphere.
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Other important organic compounds that contain oxygen are: glycerol, formaldehyde, glutaraldehyde, citric acid, acetic anhydride, acetamide, etc. Epoxides are ethers in which the oxygen atom is part of a ring of three atoms. Oxygen reacts spontaneously with many organic compounds at or below room temperature in a process called autoxidation. [7]