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A single-displacement reaction, also known as single replacement reaction or exchange reaction, is an archaic concept in chemistry. It describes the stoichiometry of some chemical reactions in which one element or ligand is replaced by atom or group. [1] [2] [3] It can be represented generically as: + +
Examples of associative mechanisms are commonly found in the chemistry of 16e square planar metal complexes, e.g. Vaska's complex and tetrachloroplatinate. The rate law is governed by the Eigen–Wilkins Mechanism. Dissociative substitution resembles the S N 1 mechanism in organic chemistry.
In the first definitive book on defence mechanisms, The Ego and the Mechanisms of Defence (1936), [9] Anna Freud enumerated the ten defence mechanisms that appear in the works of her father, Sigmund Freud: repression, regression, reaction formation, isolation, undoing, projection, introjection, turning against one's own person, reversal into the opposite, and sublimation or displacement.
An example of a simple chain reaction is the thermal decomposition of acetaldehyde (CH 3 CHO) to methane (CH 4) and carbon monoxide (CO). The experimental reaction order is 3/2, [4] which can be explained by a Rice-Herzfeld mechanism. [5] This reaction mechanism for acetaldehyde has 4 steps with rate equations for each step :
Arrow pushing or electron pushing is a technique used to describe the progression of organic chemistry reaction mechanisms. [1] It was first developed by Sir Robert Robinson.In using arrow pushing, "curved arrows" or "curly arrows" are drawn on the structural formulae of reactants in a chemical equation to show the reaction mechanism.
Examples of associative mechanisms are commonly found in the chemistry of 16e square planar metal complexes, e.g. Vaska's complex and tetrachloroplatinate. These compounds (MX 4) bind the incoming (substituting) ligand Y to form pentacoordinate intermediates MX 4 Y that in a subsequent step dissociates one of their ligands.
Examples of anomalous diffusion in nature have been observed in ultra-cold atoms, [3] harmonic spring-mass systems, [4] scalar mixing in the interstellar medium, [5] telomeres in the nucleus of cells, [6] ion channels in the plasma membrane, [7] colloidal particle in the cytoplasm, [8] [9] [10] moisture transport in cement-based materials, [11 ...
A typical representative organic reaction displaying this mechanism is the chlorination of alcohols with thionyl chloride, or the decomposition of alkyl chloroformates, the main feature is retention of stereochemical configuration. Some examples for this reaction were reported by Edward S. Lewis and Charles E. Boozer in 1952. [2]