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  2. Aniline - Wikipedia

    en.wikipedia.org/wiki/Aniline

    Likewise, it is also prone to oxidation: while freshly purified aniline is an almost colorless oil, exposure to air results in gradual darkening to yellow or red, due to the formation of strongly colored, oxidized impurities. Aniline can be diazotized to give a diazonium salt, which can then undergo various nucleophilic substitution reactions.

  3. Boyland–Sims oxidation - Wikipedia

    en.wikipedia.org/wiki/Boyland–Sims_oxidation

    The Boyland–Sims oxidation is the chemical reaction of anilines with alkaline potassium persulfate, which after hydrolysis forms ortho-hydroxyl anilines. [ 1 ] [ 2 ] [ 3 ] The reaction is generally performed in water at room temperatures or below, using equimolar quantities of reagents.

  4. Aniline (data page) - Wikipedia

    en.wikipedia.org/wiki/Aniline_(data_page)

    Aniline absorbs in the K (220 - 250 nm) and the B (250 - 290 nm) bands exhibited by benzenoid compounds. The K and B bands arise from π to π* transitions as a result of the a group containing multiple bond being attached to the benzene ring. When dissolved in ethanol, λ max for aniline is 230 nm, but in dilute aqueous acid λ max is 203 nm ...

  5. Cahill cycle - Wikipedia

    en.wikipedia.org/wiki/Cahill_cycle

    Studies have demonstrated that the glucose-alanine cycle may play a direct role in regulation of hepatic (liver) mitochondrial oxidation, particularly during periods of extended fasting. [9] Hepatic mitochondrial oxidation is a key process in the metabolism of glucose and fatty acids, involving the Citric Acid Cycle and oxidative ...

  6. Nitrosation and nitrosylation - Wikipedia

    en.wikipedia.org/wiki/Nitrosation_and_nitrosylation

    Nitrosation of aniline. N-Nitrosamines arise from the reaction of nitrite sources with amino compounds. Typically, this reaction occurs when the nucleophilic nitrogen of a secondary amine attacks the nitrogen of the electrophilic nitrosonium ion: [14] NO 2 − + 2 H + → NO + + H 2 O R 2 NH + NO + → R 2 N-NO + H +

  7. Diphenylamine - Wikipedia

    en.wikipedia.org/wiki/Diphenylamine

    The compound is a derivative of aniline, consisting of an amine bound to two phenyl groups. The compound is a colorless solid, but commercial samples are often yellow due to oxidized impurities. [5] Diphenylamine dissolves well in many common organic solvents, and is moderately soluble in water. [6] It is used mainly for its antioxidant properties

  8. Template:List of oxidation states of the elements - Wikipedia

    en.wikipedia.org/wiki/Template:List_of_oxidation...

    The oxidation states are also maintained in articles of the elements (of course), and systematically in the table {{Infobox element/symbol-to-oxidation-state}}

  9. Isotope effect on lipid peroxidation - Wikipedia

    en.wikipedia.org/wiki/Isotope_effect_on_lipid...

    Unlike catabolic oxidation of drugs, or oxidative damage to DNA or proteins (which occurs stoichiometrically), oxidation of PUFAs is particularly pernicious, proceeding through a non-enzymatic lipid peroxidation chain reaction (LPO), whereby a single ROS species can initiate a runaway autoxidation process that does not need any additional ROS ...