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Sulfur trioxide is a reagent in sulfonation reactions. Dimethyl sulfate is produced commercially by the reaction of dimethyl ether with sulfur trioxide: [20] CH 3 OCH 3 + SO 3 → (CH 3) 2 SO 4. Sulfate esters are used as detergents, dyes, and pharmaceuticals. Sulfur trioxide is generated in situ from sulfuric acid or is used as a solution in ...
Oleum (Latin oleum, meaning oil), or fuming sulfuric acid, is a term referring to solutions of various compositions of sulfur trioxide in sulfuric acid, or sometimes more specifically to disulfuric acid (also known as pyrosulfuric acid). [1] Oleums can be described by the formula ySO 3 ·H 2 O where y is the
Sulfur trioxide is the active ingredient in many sulfonation reactions. Typical conditions involve heating the aromatic compound with sulfuric acid: [2] C 6 H 6 + H 2 SO 4 → C 6 H 5 SO 3 H + H 2 O. Sulfur trioxide or its protonated derivative is the actual electrophile in this electrophilic aromatic substitution.
The industrial synthesis entails the reaction of hydrogen chloride with a solution of sulfur trioxide in sulfuric acid: [7] HCl + SO 3 → ClSO 3 H It can also be prepared by the method originally used by acid's discoverer Alexander William Williamson in 1854, [ 4 ] namely chlorination of sulfuric acid, written here for pedagogical purposes as ...
Sulfur trioxide (made by catalysis from sulfur dioxide) and sulfuric acid are similarly highly acidic and corrosive in the presence of water. Concentrated sulfuric acid is a strong dehydrating agent that can strip available water molecules and water components from sugar and organic tissue.
The Parikh–Doering oxidation is an oxidation reaction that transforms primary and secondary alcohols into aldehydes and ketones, respectively. [1] The procedure uses dimethyl sulfoxide (DMSO) as the oxidant and the solvent, activated by the sulfur trioxide pyridine complex (SO 3 •C 5 H 5 N) in the presence of triethylamine or diisopropylethylamine as base.
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Substance Formula 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Barium acetate: Ba(C 2 H 3 O 2) 2: 58.8: 62: 72: 75: 78.5: 77: 75