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A molecular ferric complex is the anion ferrioxalate, [Fe(C 2 O 4) 3] 3−, with three bidentate oxalate ions surrounding the Fe core. Relative to lower oxidation states, ferric is less common in organoiron chemistry , but the ferrocenium cation [Fe(C 2 H 5 ) 2 ] + is well known.
2 FeCl 3 + Fe → 3 FeCl 2. A traditional synthesis of anhydrous ferrous chloride is the reduction of FeCl 3 with chlorobenzene: [25] 2 FeCl 3 + C 6 H 5 Cl → 2 FeCl 2 + C 6 H 4 Cl 2 + HCl. iron(III) chloride releases chlorine gas when heated above 160 °C, generating ferrous chloride: [16] 2FeCl 3 → 2FeCl 2 + Cl 2
For example, "ferrous sulfide" can refer to the 1:1 species (mineral name troilite) or a host of Fe-deficient derivatives . The mineral magnetite ("lode stone") is a mixed-valence compound with both Fe(II) and Fe(III), Fe 3 O 4 .
Iron(II) complexes are less stable than iron(III) complexes but the preference for O-donor ligands is less marked, so that for example [Fe(NH 3) 6] 2+ is known while [Fe(NH 3) 6] 3+ is not. They have a tendency to be oxidized to iron(III) but this can be moderated by low pH and the specific ligands used. [17]
Iron(III) fluoride – FeF 3; Iron(III) oxalate – C 6 Fe 2 O 12; Iron(III) oxide – Fe 2 O 3; Iron(III) nitrate – Fe(NO 3) 3 (H 2 O) 9; Iron(III) sulfate – Fe 2 (SO 4) 3; Iron(III) thiocyanate – Fe(SCN) 3; Iron(II,III) oxide – Fe 3 O 4; Iron ferrocyanide – Fe 7 (CN) 18; Prussian blue (Iron(III) hexacyanoferrate(II)) – Fe 4 [Fe(CN ...
For example, for the compound FeCl 3, the cation, iron, can occur as Fe 2+ and Fe 3+. In order for the compound to have a net charge of zero, the cation must be Fe 3+ so that the three Cl − anions can be balanced (3+ and 3− balance to 0). Thus, this compound is termed iron(III) chloride. Another example could be the compound PbS 2.
FeOCl is prepared by heating iron(III) oxide with ferric chloride at 370 °C (698 °F) over the course of several days: [2]. Fe 2 O 3 + FeCl 3 → 3 FeOCl. Alternatively, FeOCl may be prepared by the thermal decomposition of FeCl 3 ⋅6H 2 O at 220 °C (428 °F) over the course of one hour: [3]
Ferric acetate is the iron compound with the formula Fe 3 O(O 2 CCH 3) 6 (H 2 O) 3]O 2 CCH 3. This red brown solid is the acetate salt of the coordination complex [Fe 3 O(OAc) 6 (H 2 O) 3] + (OAc − is CH 3 CO 2 −). Commonly, the salt is known as "basic iron acetate". [2] The formation of the red-brown complex was once used as a test for ...