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Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; ... Acetic Anhydride: 139.0 [6] Ethylene Dichloride: 1.25 83.5 −35 [7 ...
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
Thiophene brominates 10 7 times faster than does benzene. Acetylation occurs readily to give 2-acetylthiophene, precursor to thiophene-2-carboxylic acid and thiophene-2-acetic acid. [9] Chloromethylation and chloroethylation occur readily at the 2,5-positions. Reduction of the chloromethyl product gives 2-methylthiophene.
Acetic anhydride, or ethanoic anhydride, is the chemical compound with the formula (CH 3 CO) 2 O. Commonly abbreviated Ac 2 O , it is the simplest isolable anhydride of a carboxylic acid and is widely used as a reagent in organic synthesis .
If the two layers are heated together, the system of layers will boil at 53.3 °C, which is lower than either the boiling point of chloroform (61.2 °C) or the boiling point of water (100 °C). The vapor will consist of 97.0% chloroform and 3.0% water regardless of how much of each liquid layer is present provided both layers are indeed present.
Gas properties Std enthalpy change of formation Δ f H o gas –438.1 kJ/mol Standard molar entropy S o gas: 282.84 J/(mol K) Heat capacity c p: 63.4 J/(mol K) van der Waals' constants [2] a = 1782.3 L 2 kPa/mol 2 b = 0.1068 liter per mole
In the laboratory, it can be easily synthesized from anthranilic acid and acetic anhydride. N -Acetylanthranilic acid exhibits triboluminescence when crushed. [ 5 ] The fractured crystals have large electrical potentials between areas of high and low charge.
A yellow liquid, it is the more useful of the two isomers of acetylthiophene. It is of commercial interest as a precursor to both thiophene-2-carboxylic acid and thiophene-2-acetic acid. [2] It is prepared by the reaction of thiophene with acetyl chloride in the presence of stannic chloride. [3]