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In solution chemistry, it is common to use H + as an abbreviation for the solvated hydrogen ion, regardless of the solvent. In aqueous solution H + denotes a solvated hydronium ion rather than a proton. [9] [10] The designation of an acid or base as "conjugate" depends on the context. The conjugate acid BH + of a base B dissociates according to
A simple buffer solution consists of a solution of an acid and a salt of the conjugate base of the acid. For example, the acid may be acetic acid and the salt may be sodium acetate . The Henderson–Hasselbalch equation relates the pH of a solution containing a mixture of the two components to the acid dissociation constant , K a of the acid ...
In thermodynamics, the ebullioscopic constant K b relates molality b to boiling point elevation. [1] It is the ratio of the latter to the former: = i is the van 't Hoff factor, the number of particles the solute splits into or forms when dissolved.
In chemistry, biochemistry, and pharmacology, a dissociation constant (K D) is a specific type of equilibrium constant that measures the propensity of a larger object to separate (dissociate) reversibly into smaller components, as when a complex falls apart into its component molecules, or when a salt splits up into its component ions.
For a strong acid-strong base titration monitored by pH, we have at any i'th point in the titration = [+] [] where K w is the water autoprotolysis constant.. If titrating an acid of initial volume and concentration [+] with base of concentration [], then at any i'th point in the titration with titrant volume ,
Molar concentration (also called molarity, amount concentration or substance concentration) is a measure of the concentration of a chemical species, in particular, of a solute in a solution, in terms of amount of substance per unit volume of solution. In chemistry, the most commonly used unit for molarity is the number of moles per liter ...
When determining the stability constants of metal-ligand complexes, it is common practice to fix ligand protonation constants at values that have been determined using data obtained from metal-free solutions. Hydrolysis constants of metal ions are usually fixed at values which were obtained using ligand-free solutions.
There are three common types of chemical reaction where normality is used as a measure of reactive species in solution: In acid-base chemistry, normality is used to express the concentration of hydronium ions (H 3 O +) or hydroxide ions (OH −) in a solution. Here, 1 / f eq is an integer value. Each solute can produce one or more ...