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Sodium hypophosphite (NaPO 2 H 2, also known as sodium phosphinate) is the sodium salt of hypophosphorous acid and is often encountered as the monohydrate, NaPO 2 H 2 ·H 2 O. It is a solid at room temperature, appearing as odorless white crystals. It is soluble in water, and easily absorbs moisture from the air.
An amphiprotic molecule (or ion) can either donate or accept a proton, thus acting either as an acid or a base. Water, amino acids, hydrogencarbonate ion (or bicarbonate ion) HCO − 3, dihydrogen phosphate ion H 2 PO − 4, and hydrogensulfate ion (or bisulfate ion) HSO − 4 are common examples of amphiprotic species. Since they can donate a ...
The salt is obtained by partial neutralization of phosphoric acid. The pK a of monosodium phosphate is 6.8-7.2 (depending on the physicochemical characteristics during pK a determination). [2] Heating this salt above 169 °C gives disodium pyrophosphate: 2 NaH 2 PO 4 → Na 2 H 2 P 2 O 7 + H 2 O. When heated at 550 °C, anhydrous trisodium ...
A typical derivative is the salt [NH 4][HP(O) 2 OH]. [7] [6] Many related salts are known, e.g., RbHPHO 3, CsHPHO 3, TlHPHO 3. These salts are prepared by treating phosphorous acid with the metal carbonate. These compounds contain a layer polymeric anion consisting of HPO 3 tetrahedra linked by hydrogen bonds. These layers are interleaved by ...
Sodium atoms have 11 electrons, one more than the stable configuration of the noble gas neon. As a result, sodium usually forms ionic compounds involving the Na + cation. [1] Sodium is a reactive alkali metal and is much more stable in ionic compounds. It can also form intermetallic compounds and organosodium compounds.
Note that each extra phosphoric unit adds one extra P atom, three extra O atoms, and either one extra hydrogen atom or an extra negative charge. Branched polyphosphoric acids give similarly branched polyphosphate anions. The simplest example of this is triphosphono phosphate [OP(OPO 3) 3] 9− and its partially dissociated versions.
4 RR′R″ where one or more hydrogen atoms are replaced by organic groups. An example is trimethyl phosphate, (CH 3) 3 PO 4. The term also refers to the trivalent functional group OP(O-) 3 in such esters. Phosphates may contain sulfur in place of one or more oxygen atoms (thiophosphates and organothiophosphates).
The acid is prepared industrially via a two step process: Firstly, elemental white phosphorus reacts with alkali and alkaline earth hydroxides to give an aqueous solution of hypophosphites: P 4 + 4 OH − + 4 H 2 O → 4 H 2 PO − 2 + 2 H 2. Any phosphites produced in this step can be selectively precipitated out by treatment with calcium salts.