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A fraction in chemistry is a quantity collected from a batch of a substance in a fractionating separation process. In such a process, a mixture is separated into fractions, which have compositions that vary according to a gradient. A fraction can be defined as a group of chemicals that have similar boiling points.
[1] [2] Fractions are collected based on differences in a specific property of the individual components. A common trait in fractionations is the need to find an optimum between the amount of fractions collected and the desired purity in each fraction. Fractionation makes it possible to isolate more than two components in a mixture in a single run.
Mole fraction is numerically identical to the number fraction, which is defined as the number of particles of a constituent N i divided by the total number of all molecules N tot. Whereas mole fraction is a ratio of amounts to amounts (in units of moles per moles), molar concentration is a quotient of amount to volume (in units of moles per litre).
The calculations involved in the design of petroleum fractionation columns require in the usual practice the use of numerable charts, tables, and complex empirical equations. In recent years, however, a considerable amount of work has been done to develop efficient and reliable computer-aided design procedures for fractional distillation. [8]
In chemistry, the lever rule is a formula used to determine the mole fraction (x i) or the mass fraction (w i) of each phase of a binary equilibrium phase diagram. It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line. [1]
The abundance of the chemical elements is a measure of the occurrences of the chemical elements relative to all other elements in a given environment. Abundance is measured in one of three ways: by mass fraction (in commercial contexts often called weight fraction), by mole fraction (fraction of atoms by numerical count, or sometimes fraction of molecules in gases), or by volume fraction.
Unit fractions can also be expressed using negative exponents, as in 2 −1, which represents 1/2, and 2 −2, which represents 1/(2 2) or 1/4. A dyadic fraction is a common fraction in which the denominator is a power of two, e.g. 1 / 8 = 1 / 2 3 . In Unicode, precomposed fraction characters are in the Number Forms block.
A concise four-page summary of the most important material in the Green Book was published in the July–August 2011 issue of Chemistry International, the IUPAC news magazine. The second edition of the Green Book (ISBN 0-632-03583-8) was first published in 1993. It was reprinted in 1995, 1996, and 1998.
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