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Carnot engine diagram (modern) - where an amount of heat Q H flows from a high temperature T H furnace through the fluid of the "working body" (working substance) and the remaining heat Q C flows into the cold sink T C, thus forcing the working substance to do mechanical work W on the surroundings, via cycles of contractions and expansions.
Thermodynamics and statistical mechanics. {}: CS1 maint: multiple names: authors list Translated by J. Kestin (1956) New York: Academic Press. Ehrenfest, Paul and Tatiana (1912). The conceptual foundations of the statistical approach in mechanics .
The first part of the book starts by presenting the problem thermodynamics is trying to solve, and provides the postulates on which thermodynamics is founded. It then develops upon this foundation to discuss reversible processes, heat engines, thermodynamics potentials, Maxwell's relations, stability of thermodynamics systems, and first-order phase transitions.
By conservation of energy, the maximum amount of work/energy that can be extracted from a heat engine = difference between heat/energy taken from the hotter reservoir (Qh) and heat/energy lost to the colder reservoir (Qc) = Qh - Qc. The efficiency of an engine is defined as: η = work out/ energy in = (Qh - Qc)/Qh = 1 - Qc/Qh So what is Qc/Qh?
A Carnot cycle is an ideal thermodynamic cycle proposed by French physicist Sadi Carnot in 1824 and expanded upon by others in the 1830s and 1840s. By Carnot's theorem, it provides an upper limit on the efficiency of any classical thermodynamic engine during the conversion of heat into work, or conversely, the efficiency of a refrigeration system in creating a temperature difference through ...
A heat engine is a system that converts heat to usable energy, particularly mechanical energy, which can then be used to do mechanical work. [1] [2] While originally conceived in the context of mechanical energy, the concept of the heat engine has been applied to various other kinds of energy, particularly electrical, since at least the late 19th century.
For quasi-static and reversible processes, the first law of thermodynamics is: d U = δ Q − δ W {\displaystyle dU=\delta Q-\delta W} where δQ is the heat supplied to the system and δW is the work done by the system.
Then if is more efficient than , the machine will violate the second law of thermodynamics. Since a Carnot heat engine is a reversible heat engine, and all reversible heat engines operate with the same efficiency between the same reservoirs, we have the first part of Carnot's theorem: