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Thermal diffusivity is a contrasting measure to thermal effusivity. [6] [7] In a substance with high thermal diffusivity, heat moves rapidly through it because the substance conducts heat quickly relative to its volumetric heat capacity or 'thermal bulk'. Thermal diffusivity is often measured with the flash method.
The transient hot wire method has advantage over the other thermal conductivity methods, since there is a fully developed theory and there is no calibration or single-point calibration. Furthermore, because of the very small measuring time (1 s) there is no convection present in the measurements and only the thermal conductivity of the fluid is ...
The higher the thermal diffusivity of the sample, the faster the energy reaches the backside. A laser flash apparatus (LFA) to measure thermal diffusivity over a broad temperature range, is shown on the right hand side. In a one-dimensional, adiabatic case the thermal diffusivity is calculated from this temperature rise as follows:
The heat generated dissipates into the sample on both sides of the sensor, at a rate depending on the thermal transport properties of the material. By recording temperature vs. time response in the sensor, the thermal conductivity, thermal diffusivity and specific heat capacity of the material can be calculated.
Small values of the Prandtl number, Pr ≪ 1, means the thermal diffusivity dominates. Whereas with large values, Pr ≫ 1, the momentum diffusivity dominates the behavior. For example, the listed value for liquid mercury indicates that the heat conduction is more significant compared to convection, so thermal diffusivity is dominant. However ...
Thermal effusivity and thermal diffusivity are related quantities; respectively a product versus a ratio of a material's intensive heat transport and storage properties. The diffusivity appears explicitly in the heat equation, which is an energy conservation equation , and measures the speed at which thermal equilibrium can be reached by a body ...
Mostly nitrogen is used and for temperatures above 600 °C, argon can be utilized to minimize heat loss due to the low thermal conductivity of argon. Air or pure oxygen can be used for oxidative tests like oxidative induction time and He is used for very low temperatures due to the low boiling temperature (~4.2K at 101.325 kPa [ 24 ] ).
Typically, a compound's diffusion coefficient is ~10,000× as great in air as in water. Carbon dioxide in air has a diffusion coefficient of 16 mm 2 /s, and in water its diffusion coefficient is 0.0016 mm 2 /s. [1] [2] Diffusivity has dimensions of length 2 / time, or m 2 /s in SI units and cm 2 /s in CGS units.