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The Knudsen number is a dimensionless number defined as =, where = mean free path [L 1], = representative physical length scale [L 1].. The representative length scale considered, , may correspond to various physical traits of a system, but most commonly relates to a gap length over which thermal transport or mass transport occurs through a gas phase.
For example, it is used to calculate flow through circular and non-circular tubes in order to examine flow conditions (i.e., the Reynolds number). In those cases, the characteristic length is the diameter of the pipe or, in case of non-circular tubes, its hydraulic diameter D h {\displaystyle D_{h}} :
Dimensionless numbers (or characteristic numbers) have an important role in analyzing the behavior of fluids and their flow as well as in other transport phenomena. [1] They include the Reynolds and the Mach numbers, which describe as ratios the relative magnitude of fluid and physical system characteristics, such as density, viscosity, speed of sound, and flow speed.
Schematic drawing of a molecule in a cylindrical pore in the case of Knudsen diffusion; are indicated the pore diameter (d) and the free path of the particle (l).Knudsen diffusion, named after Martin Knudsen, is a means of diffusion that occurs when the scale length of a system is comparable to or smaller than the mean free path of the particles involved.
Using the number density of an ideal gas at 0 °C and 1 atm as a yardstick: n 0 = 1 amg = 2.686 7774 × 10 25 m −3 is often introduced as a unit of number density, for any substances at any conditions (not necessarily limited to an ideal gas at 0 °C and 1 atm).
The hydraulic diameter, D H, is a commonly used term when handling flow in non-circular tubes and channels. Using this term, one can calculate many things in the same way as for a round tube. When the cross-section is uniform along the tube or channel length, it is defined as [1] [2] =, where
D 50: Mass-median-diameter (MMD). The log-normal distribution mass median diameter. The MMD is considered to be the average particle diameter by mass. σ g: Geometric standard deviation. This value is determined mathematically by the equation: σ g = D 84.13 /D 50 = D 50 /D 15.87. The value of σ g determines the slope of the least-squares ...
The kinetic diameter is not the same as atomic diameter defined in terms of the size of the atom's electron shell, which is generally a lot smaller, depending on the exact definition used. Rather, it is the size of the sphere of influence that can lead to a scattering event. [1] Kinetic diameter is related to the mean free path of molecules in ...