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The reaction of (MDI) and polyol takes place at higher temperatures compared with the reaction temperature for the manufacture of PUR. At these elevated temperatures and in the presence of specific catalysts, MDI will first react with itself, producing a stiff, ring molecule, which is a reactive intermediate (a tri-isocyanate isocyanurate compound).
Moisture cured polyurethane–urea coatings have been made by reacting 1,2,3-triazole rich polyether polyols with HMDI at NCO/OH eq. ratio of 1.2 to obtain isocyanate-terminated polyurethane prepolymers. The prepolymers were cured under atmospheric moisture to make polyurethane–urea free films.
A polyurethane is typically produced by reacting a polymeric isocyanate with a polyol. [3] Since a polyurethane contains two types of monomers, which polymerize one after the other, they are classed as alternating copolymers. Both the isocyanates and polyols used to make a polyurethane contain two or more functional groups per molecule.
The flexible polyurethane foam (FPUF) is produced from the reaction of polyols and isocyanates, a process pioneered in 1937. [7] Depending on the application the foam will be used for, a series of additives are necessary to produce high-quality PU foam products. FPUF is a versatile material that can be tailored to exhibit different properties.
Spray foam (expanding foam in the UK) is a chemical product created by a chemical reaction of two component parts, commonly referred to as side A and side B. [1] Side A contains very reactive chemicals known as isocyanate. Side B contains a polyol, which reacts with isocyanates to make polyurethane, and a mixture of other chemicals, including ...
TPU is a block copolymer consisting of alternating sequences of hard and soft segments or domains formed by the reaction of (1) diisocyanates with short-chain diols (so-called chain extenders) and (2) diisocyanates with long-chain diols. By varying the ratio, structure and/or molecular weight of the reaction compounds, an enormous variety of ...
The isocyanate functional group. In organic chemistry, isocyanate is the functional group with the formula R−N=C=O. Organic compounds that contain an isocyanate group are referred to as isocyanates. An organic compound with two isocyanate groups is known as a diisocyanate.
In organic chemistry, a polyol is an organic compound containing multiple hydroxyl groups (−OH). The term "polyol" can have slightly different meanings depending on whether it is used in food science or polymer chemistry. Polyols containing two, three and four hydroxyl groups are diols, [1] triols, [2] and tetrols, [3] [4] respectively.