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If the fluid is a gas, certain properties of the gas influence the drag and those properties must also be taken into account. Those properties are conventionally considered to be the absolute temperature of the gas, and the ratio of its specific heats. These two properties determine the speed of sound in the gas at its given temperature.
Under these conditions, p 1 V 1 γ = p 2 V 2 γ, where γ is defined as the heat capacity ratio, which is constant for a calorifically perfect gas. The value used for γ is typically 1.4 for diatomic gases like nitrogen (N 2) and oxygen (O 2), (and air, which is 99% diatomic).
Absolute cylinder pressure is used to calculate the dynamic compression ratio, using the following formula: = where is a polytropic value for the ratio of specific heats for the combustion gases at the temperatures present (this compensates for the temperature rise caused by compression, as well as heat lost to the cylinder)
A major use of the integrated equation is to estimate a new equilibrium constant at a new absolute temperature assuming a constant standard enthalpy change over the temperature range. To obtain the integrated equation, it is convenient to first rewrite the Van 't Hoff equation as [ 2 ]
Entropy cannot be measured directly. The change in entropy with respect to pressure at a constant temperature is the same as the negative change in specific volume with respect to temperature at a constant pressure, for a simple compressible system. Maxwell relations in thermodynamics are often used to derive thermodynamic relations. [2]
The first of the cooling load factors used in this method is the CLTD, or the Cooling Load Temperature Difference. This factor is used to represent the temperature difference between indoor and outdoor air with the inclusion of the heating effects of solar radiation. [1] [5] The second factor is the CLF, or the cooling load factor.
The Boltzmann constant (k B or k) is the proportionality factor that relates the average relative thermal energy of particles in a gas with the thermodynamic temperature of the gas. [2] It occurs in the definitions of the kelvin (K) and the gas constant , in Planck's law of black-body radiation and Boltzmann's entropy formula , and is used in ...
The maximum work is thus regarded as the diminution of the free, or available, energy of the system (Gibbs free energy G at T = constant, P = constant or Helmholtz free energy F at T = constant, V = constant), whilst the heat given out is usually a measure of the diminution of the total energy of the system (internal energy).