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In chemistry, a chemical oscillator is a complex mixture of reacting chemical compounds in which the concentration of one or more components exhibits periodic changes. They are a class of reactions that serve as an example of non-equilibrium thermodynamics with far-from-equilibrium behavior.
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
Oscillation is the repetitive or periodic variation, typically in time, of some measure about a central value (often a point of equilibrium) or between two or more different states. Familiar examples of oscillation include a swinging pendulum and alternating current. Oscillations can be used in physics to approximate complex interactions, such ...
In practice N is set to 1 cycle and t = T = time period for 1 cycle, to obtain the more useful relation: = / Hz = s −1 [T] −1: Angular frequency/ pulsatance ω = = / Hz = s −1 [T] −1: Oscillatory velocity v, v t, v: Longitudinal waves:
The period T is the time taken to complete one cycle of an oscillation or rotation. The frequency and the period are related by the equation [ 4 ] f = 1 T . {\displaystyle f={\frac {1}{T}}.} The term temporal frequency is used to emphasise that the frequency is characterised by the number of occurrences of a repeating event per unit time.
The equation for describing the period: = shows the period of oscillation is independent of the amplitude, though in practice the amplitude should be small. The above equation is also valid in the case when an additional constant force is being applied on the mass, i.e. the additional constant force cannot change the period of oscillation.
The period, the time for one complete oscillation, is given by the expression = =, which is a good approximation of the actual period when is small. Notice that in this approximation the period τ {\displaystyle \tau } is independent of the amplitude θ 0 {\displaystyle \theta _{0}} .
Time evolution of the probability distribution (and phase, shown as color) of a coherent state with |α|=3. The coherent states (also known as Glauber states) of the harmonic oscillator are special nondispersive wave packets , with minimum uncertainty σ x σ p = ℏ ⁄ 2 , whose observables ' expectation values evolve like a classical system.