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Sulfur (16 S) has 23 known isotopes with mass numbers ranging from 27 to 49, four of which are stable: 32 S (95.02%), 33 S (0.75%), 34 S (4.21%), and 36 S (0.02%). The preponderance of sulfur-32 is explained by its production from carbon-12 plus successive fusion capture of five helium-4 nuclei, in the so-called alpha process of exploding type II supernovas (see silicon burning).
Of the 25 known isotopes of sulfur, four are stable. [1] In order of their abundance, those isotopes are 32 S (94.93%), 34 S (4.29%), 33 S (0.76%), and 36 S (0.02%). [2] The δ 34 S value refers to a measure of the ratio of the two most common stable sulfur isotopes, 34 S: 32 S, as measured in a sample against that same ratio as measured in a known reference standard.
This is an accepted version of this page This is the latest accepted revision, reviewed on 6 January 2025. This article is about the chemical element. For other uses, see Sulfur (disambiguation). Chemical element with atomic number 16 (S) Sulfur, 16 S Sulfur Alternative name Sulphur (British spelling) Allotropes see Allotropes of sulfur Appearance Lemon yellow sintered microcrystals Standard ...
With the discovery of oxygen isotopes in 1929, a situation arose where chemists based their calculations on the average atomic mass (atomic weight) of oxygen whereas physicists used the mass of the predominant isotope of oxygen, oxygen-16. This discrepancy became undesired and a unification between the chemistry and physics was necessary. [13]
Sulfur isotope fractionations are usually measured in terms of δ 34 S due to its higher abundance (4.25%) compared to the other stable isotopes of sulfur, though δ 33 S is also sometimes measured. Differences in sulfur isotope ratios are thought to exist primarily due to kinetic fractionation during reactions and transformations.
Isotope geochemistry is an aspect of geology based upon the study of natural variations in the relative abundances of isotopes of various elements.Variations in isotopic abundance are measured by isotope-ratio mass spectrometry, and can reveal information about the ages and origins of rock, air or water bodies, or processes of mixing between them.
This infobox contains the table of § Main isotopes, and the § Standard atomic weight. For example, {{Infobox uranium isotopes}}, as used on page Isotopes of uranium. The main isotopes table is reused in the regular Infobox: {{Infobox uranium}}.
The standard atomic weight of a chemical element (symbol A r °(E) for element "E") is the weighted arithmetic mean of the relative isotopic masses of all isotopes of that element weighted by each isotope's abundance on Earth. For example, isotope 63 Cu (A r = 62.929) constitutes 69% of the copper on Earth, the rest being 65 Cu (A r = 64.927), so