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The runners-up used are also cyclic acetals with 1,2‑hydroxythiols or dithioglycols – the so-called O,S– or S,S-acetals. Ethylene glycol 1,3‑Propadiol Overall, trans-acetalation plays a lesser role in forming protective acetals; they are formed as a rule from glycols through dehydration.
Due to its large surface area and high volume of contained hydrogen gas, dry, activated Raney nickel is a pyrophoric material that requires handling under an inert atmosphere. Raney nickel is typically supplied as a 50% slurry in water. Even after reaction, residual Raney nickel contains significant amounts of hydrogen gas and may spontaneously ...
Acetals are stable compared to hemiacetals but their formation is a reversible equilibrium as with esters.As a reaction to create an acetal proceeds, water must be removed from the reaction mixture, for example, with a Dean–Stark apparatus, lest it hydrolyse the product back to the hemiacetal.
Dioxolane is a heterocyclic acetal with the chemical formula (CH 2) 2 O 2 CH 2. It is related to tetrahydrofuran (THF) by replacement of the methylene group (CH 2) at the 2-position with an oxygen atom. The corresponding saturated 6-membered C 4 O 2 rings are called dioxanes.
A Schlenk line with four ports. The cold trap is on the right. Close-up view, showing the double-oblique stopcock, which allows vacuum (rear line) or inert gas (front line) to be selected. The Schlenk line (also vacuum gas manifold) is a commonly used chemistry apparatus developed by Wilhelm Schlenk. [1] It consists of a dual manifold with ...
In organic chemistry, an acetonide is the functional group composed of the cyclic ketal of a diol with acetone. The more systematic name for this structure is an isopropylidene ketal. Acetonide is a common protecting group for 1,2- and 1,3-diols. [1] The protecting group can be removed by hydrolysis of the ketal using dilute aqueous acid.
The four phosphorus atoms are at the corners of a tetrahedron surrounding the palladium(0) center. This structure is typical for four-coordinate 18 e − complexes. [2] The corresponding complexes Ni(PPh 3) 4 and Pt(PPh 3) 4 are also well known.
Tetrahydropyran (THP) is the organic compound consisting of a saturated six-membered ring containing five carbon atoms and one oxygen atom. It is named by reference to pyran, which contains two double bonds, and may be produced from it by adding four hydrogens.