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A polytropic process is a thermodynamic process that obeys the relation: = where p is the pressure , V is volume , n is the polytropic index , and C is a constant. The polytropic process equation describes expansion and compression processes which include heat transfer.
The particular choice of a polytropic gas as given above makes the mathematical statement of the problem particularly succinct and leads to the Lane–Emden equation. The equation is a useful approximation for self-gravitating spheres of plasma such as stars, but typically it is a rather limiting assumption.
The normalized density as a function of scale length for a wide range of polytropic indices. In astrophysics, a polytrope refers to a solution of the Lane–Emden equation in which the pressure depends upon the density in the form = (+) / = + /, where P is pressure, ρ is density and K is a constant of proportionality. [1]
An example of a cycle of idealized thermodynamic processes which make up the Stirling cycle. A quasi-static thermodynamic process can be visualized by graphically plotting the path of idealized changes to the system's state variables. In the example, a cycle consisting of four quasi-static processes is shown.
where is the specific energy, is the specific volume, is the specific entropy, is the molecular mass, here is considered a constant (polytropic process), and can be shown to correspond to the heat capacity ratio. This equation can be shown to be consistent with the usual equations of state employed by thermodynamics.
This is a list of unsolved problems in chemistry. Problems in chemistry are considered unsolved when an expert in the field considers it unsolved or when several experts in the field disagree about a solution to a problem.
This is an energy balance which defines the position of the moving interface. Note that this evolving boundary is an unknown (hyper-)surface; hence, Stefan problems are examples of free boundary problems. Analogous problems occur, for example, in the study of porous media flow, mathematical finance and crystal growth from monomer solutions. [1]
n=0 is a constant-pressure process because the polytropic equation reduces to P = constant since v^0 = 1. I also don't understand the comments about negative polytropic exponent. Look at the derivation regarding the energy transfer ratio. For example, a process would have a polytropic exponent of -1 if it has an energy transfer ratio of 6.