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The electron–hole pair is the fundamental unit of generation and recombination in inorganic semiconductors, corresponding to an electron transitioning between the valence band and the conduction band where generation of an electron is a transition from the valence band to the conduction band and recombination leads to a reverse transition.
Especially in proteins, electron transfer often involves hopping of an electron from one redox-active center to another one. The hopping pathway, which can be viewed as a vector, guides and facilitates ET within an insulating matrix. Typical redox centers are iron-sulfur clusters, e.g. the 4Fe-4S ferredoxins. These sites are often separated by ...
The Pauli exclusion principle limits the number of electrons in a single orbital to two, and the bands are filled beginning with the lowest energy. In solid-state physics and solid-state chemistry , a band gap , also called a bandgap or energy gap , is an energy range in a solid where no electronic states exist.
Charge transfer coefficient, and symmetry factor (symbols α and β, respectively) are two related parameters used in description of the kinetics of electrochemical reactions. They appear in the Butler–Volmer equation and related expressions.
The SI unit of velocity is m/s, and the SI unit of electric field is V/m. Therefore the SI unit of mobility is (m/s)/(V/m) = m 2 /(V⋅s). However, mobility is much more commonly expressed in cm 2 /(V⋅s) = 10 −4 m 2 /(V⋅s). Mobility is usually a strong function of material impurities and temperature, and is determined empirically.
In complexes of metals with these d-electron configurations, the non-bonding and anti-bonding molecular orbitals can be filled in two ways: one in which as many electrons as possible are put in the non-bonding orbitals before filling the anti-bonding orbitals, and one in which as many unpaired electrons as possible are put in. The former case ...
A Proton-coupled electron transfer (PCET) is a chemical reaction that involves the transfer of electrons and protons from one atom to another. The term was originally coined for single proton, single electron processes that are concerted, [ 1 ] but the definition has relaxed to include many related processes.
(The first process can even precipitate the second one.) Like IC electrons, Auger electrons have a discrete energy, resulting in a sharp energy peak in the spectrum. Electron capture also involves an inner shell electron, which in this case is retained in the nucleus (changing the atomic number) and leaving the atom (not nucleus) in an excited ...