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By definition, pOH is the negative logarithm (to the base 10) of the hydroxide ion concentration (mol/L). pOH values can be derived from pH measurements and vice-versa. The concentration of hydroxide ions in water is related to the concentration of hydrogen ions by. where KW is the self-ionization constant of water.
With pOH obtained from the pOH formula given above, the pH of the base can then be calculated from =, where pK w = 14.00. A weak base persists in chemical equilibrium in much the same way as a weak acid does, with a base dissociation constant (K b) indicating the strength of the base. For example, when ammonia is put in water, the following ...
For example, ammonia solutions have a pH greater than 7 due to the reaction NH 3 + H + ⇌ NH + 4, which decreases the hydrogen cation concentration, which increases the hydroxide ion concentration. pOH can be kept at a nearly constant value with various buffer solutions. Schematic representation of the bihydroxide ion [2]
The Henderson–Hasselbalch equation can be used to estimate the pH of a buffer solution by approximating the actual concentration ratio as the ratio of the analytical concentrations of the acid and of a salt, MA. The equation can also be applied to bases by specifying the protonated form of the base as the acid. For example, with an amine,
A pH indicator is a halochromic chemical compound added in small amounts to a solution so the pH (acidity or basicity) of the solution can be determined visually or spectroscopically by changes in absorption and/or emission properties. [1] Hence, a pH indicator is a chemical detector for hydronium ions (H 3 O +) or hydrogen ions (H +) in the ...
Polonium hydride (also known as polonium dihydride, hydrogen polonide, or polane) is a chemical compound with the formula Po H 2. It is a liquid at room temperature, the second hydrogen chalcogenide with this property after water. It is very unstable chemically and tends to decompose into elemental polonium and hydrogen.
Phosphite ester. In organic chemistry, a phosphite ester or organophosphite usually refers to an organophosphorous compound with the formula P (OR) 3. They can be considered as esters of an unobserved tautomer phosphorous acid, H 3 PO 3, with the simplest example being trimethylphosphite, P (OCH 3) 3. Some phosphites can be considered esters of ...
Phosphinous acid is the inorganic compound with the formula H 2 POH. It exists, fleetingly, as a mixture with its less stable tautomer H 3 PO (phosphine oxide). This mixture has been generated by low temperature oxidation of phosphine with ozone. [1] H 2 POH is mainly of pedagogical interest.